Synthesis and structure of an open-framework zincophosphate   [C6N4H22][ZnPO4](4)

doi:10.1006/jssc.2001.9498

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)
	Zhao, YN ; Ju, J ; Chen, XM ; Li, XH ; Wang, RJ ; Mai, ZH
刊名	journal of solid state chemistry
	2002
关键词	LAYERED ZINC PHOSPHATE HYDROTHERMAL SYNTHESIS METAL PHOSPHATES TETRAHEDRA
DOI	10.1006/jssc.2001.9498
英文摘要	A new zincophosphate [C6N4H22][ZnPO4](4) 1 has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. It crystallized in the triclinic space group P1 with a = 9.784(2) Angstrom, b = 10.074(2) Angstrom, c = 8.0573(16) Angstrom, alpha = 121.62(3)degrees, beta = 119.20(3)degrees, gamma = 98.37(3)degrees, V = 496.96(17) Angstrom(3), Z = 1. Refinement gave R-1 = 0.0651, wR(2) = 0.1476 for observed data. The zinc and phosphorous atoms are tetrahedrally coordinated by oxygen atoms with a Zn to P ratio of 1. The structure of 1 is constructed by strictly alternating linking of ZnO4 and PO4 with four-membered rings as the secondary building units. The four-membered rings are further connected in three styles: sharing zinc atoms to form a chain structure, connected using vertices to form an undulating chain, and a 4-1 connection. These connections give a complex three-dimensional eight-membered ring channel system. (C) 2002 Elsevier Science (USA).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000175169200026&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; Chemistry, Physical; SCI(E); 11; ARTICLE; 1; 182-186; 165
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/209298]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhao, YN,Ju, J,Chen, XM,et al. Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)[J]. journal of solid state chemistry,2002.
APA	Zhao, YN,Ju, J,Chen, XM,Li, XH,Wang, RJ,&Mai, ZH.(2002).Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4).journal of solid state chemistry.
MLA	Zhao, YN,et al."Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)".journal of solid state chemistry (2002).