A Robust Microfluidic Device for the Synthesis and Crystal Growth of Organometallic Polymers with Highly Organized Structures | |
Liu, Xiao ; Yi, Qiaolian ; Han, Yongzhen ; Liang, Zhenning ; Shen, Chaohua ; Zhou, Zhengyang ; Sun, Jun-liang ; Li, Yizhi ; Du, Wenbin ; Cao, Rui | |
刊名 | angewandte chemie international edition |
2015 | |
关键词 | crystal growth polymers silver solid-state structures X-ray diffraction FREE INTERFACE DIFFUSION PROTEIN CRYSTALLIZATION SUPRAMOLECULAR SYNTHONS FRAMEWORK CRYSTALS SILVER ARRAYS MICROCHANNELS CYCLOADDITION OPTIMIZATION DIFFRACTION |
DOI | 10.1002/anie.201411008 |
英文摘要 | A simple and robust microfluidic device was developed to synthesize organometallic polymers with highly organized structures. The device is compatible with organic solvents. Reactants are loaded into pairs of reservoirs connected by a 15cm long microchannel prefilled with solvents, thus allowing long-term counter diffusion for self-assembly of organometallic polymers. The process can be monitored, and the resulting crystalline polymers are harvested without damage. The device was used to synthesize three insoluble silver acetylides as single crystals of X-ray diffraction quality. Importantly, for the first time, the single-crystal structure of silver phenylacetylide was determined. The reported approach may have wide applications, such as crystallization of membrane proteins, synthesis and crystal growth of organic, inorganic, and polymeric coordination compounds, whose single crystals cannot be obtained using traditional methods.; Chemistry, Multidisciplinary; SCI(E); EI; 1; ARTICLE; wenbin@im.ac.cn; ruicao@ruc.edu.cn; 6; 1846-1850; 54 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/206383] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Liu, Xiao,Yi, Qiaolian,Han, Yongzhen,et al. A Robust Microfluidic Device for the Synthesis and Crystal Growth of Organometallic Polymers with Highly Organized Structures[J]. angewandte chemie international edition,2015. |
APA | Liu, Xiao.,Yi, Qiaolian.,Han, Yongzhen.,Liang, Zhenning.,Shen, Chaohua.,...&Cao, Rui.(2015).A Robust Microfluidic Device for the Synthesis and Crystal Growth of Organometallic Polymers with Highly Organized Structures.angewandte chemie international edition. |
MLA | Liu, Xiao,et al."A Robust Microfluidic Device for the Synthesis and Crystal Growth of Organometallic Polymers with Highly Organized Structures".angewandte chemie international edition (2015). |
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