Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from   reaction of 1,4-dilithio-1,3-dienes with aldehydes

doi:10.1021/ol0261478

CORC > 北京大学 > 化学与分子工程学院

	Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes
	Chen, JL ; Song, QL ; Li, PX ; Guan, HR ; Jin, XL ; Xi, ZF
刊名	organic letters
	2002
关键词	METAL-PROMOTED CYCLIZATION ONE-POT SYNTHESIS EFFICIENT SYNTHESIS DERIVATIVES ALKYNES DIHYDROFURANS RESOLUTION ETHERS ENYNES DIYNES
DOI	10.1021/ol0261478
英文摘要	Reaction of 1,4-dilithio-1,3-diene derivatives with 2 equiv of aldehydes affords polysubstituted 2,5-dihydrofurans in good to high yields with perfect regio- and stereoselectivities. Hexa-2,4-diene-1,6-dialcoholates are proposed as the first intermediates, which undergo a cyclization and subsequent elimination of Li2O to generate the 2,5-dihydrofuran derivatives.; Chemistry, Organic; SCI(E); PubMed; 35; ARTICLE; 13; 2269-2271; 4
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/200453]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chen, JL,Song, QL,Li, PX,et al. Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes[J]. organic letters,2002.
APA	Chen, JL,Song, QL,Li, PX,Guan, HR,Jin, XL,&Xi, ZF.(2002).Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes.organic letters.
MLA	Chen, JL,et al."Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes".organic letters (2002).