Lewis acid mediated reactions of zirconacyclopentadienes with aldehydes: one-pot synthetic route to indene and cyclopentadiene derivatives from aldehydes and benzyne or alkynes | |
Zhao, CJ ; Li, PX ; Cao, XY ; Xi, ZF | |
刊名 | chemistry a european journal |
2002 | |
关键词 | aldehydes cyclopentadienes Lewis acids synthetic methods zirconium ORGANIC-SYNTHESIS METAL-COMPLEXES ZIRCONIUM ALKENES ZIRCONACYCLES CO CYCLOPENTENONE REARRANGEMENT CYCLOADDITION ACTIVATION |
DOI | 10.1002/1521-3765(20020916)8:18<4292::AID-CHEM4292>3.0.CO;2-G |
英文摘要 | One-pot procedures for the preparation of highly substituted indenes., tetrahydroindenes, and cyclopentadienes have been developed by using a combination of zirconocene-mediated C-C-bond-forming reactions with Lewis acid mediated activation of carbonyl groups. The carbonyl groups of aldehydes were deoxygenated in the reaction and behaved formally as a one-carbon unit. A variety of Lewis acids were checked and showed different reactivities in this reaction.; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 35; ARTICLE; 18; 4292-4298; 8 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/200414] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhao, CJ,Li, PX,Cao, XY,et al. Lewis acid mediated reactions of zirconacyclopentadienes with aldehydes: one-pot synthetic route to indene and cyclopentadiene derivatives from aldehydes and benzyne or alkynes[J]. chemistry a european journal,2002. |
APA | Zhao, CJ,Li, PX,Cao, XY,&Xi, ZF.(2002).Lewis acid mediated reactions of zirconacyclopentadienes with aldehydes: one-pot synthetic route to indene and cyclopentadiene derivatives from aldehydes and benzyne or alkynes.chemistry a european journal. |
MLA | Zhao, CJ,et al."Lewis acid mediated reactions of zirconacyclopentadienes with aldehydes: one-pot synthetic route to indene and cyclopentadiene derivatives from aldehydes and benzyne or alkynes".chemistry a european journal (2002). |
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