Highly diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to N-sulfinyl imines: Enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines | |
Dong, Changqing ; Mo, Fanyang ; Wang, Jianbo | |
刊名 | journal of organic chemistry
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2008 | |
关键词 | C-H INSERTION SUBSTITUTED GAMMA-LACTAMS BETA-AMINO ACIDS STEREOSELECTIVE-SYNTHESIS ASYMMETRIC-SYNTHESIS RING EXPANSION WOLFF REARRANGEMENT CARBONYL-COMPOUNDS CHLOROSULFONYL ISOCYANATE NUCLEOPHILIC-ADDITION |
DOI | 10.1021/jo702275a |
英文摘要 | [GRAPHICS] The highly enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines has been achieved by diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to chiral N-sulfinyl imines, followed by photoinduced Wolff rearrangement or Rh(II)-catalyzed intramolecular N-H insertion.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000253595100035&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); PubMed; 29; ARTICLE; 5; 1971-1974; 73 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/199245] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Dong, Changqing,Mo, Fanyang,Wang, Jianbo. Highly diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to N-sulfinyl imines: Enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines[J]. journal of organic chemistry,2008. |
APA | Dong, Changqing,Mo, Fanyang,&Wang, Jianbo.(2008).Highly diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to N-sulfinyl imines: Enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines.journal of organic chemistry. |
MLA | Dong, Changqing,et al."Highly diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to N-sulfinyl imines: Enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines".journal of organic chemistry (2008). |
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