Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C   Bonds: A New Approach toward Phenanthrols and Naphthols

doi:10.1002/anie.201209269

CORC > 北京大学 > 化学与分子工程学院

	Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C Bonds: A New Approach toward Phenanthrols and Naphthols
	Xia, Ying ; Qu, Peiyuan ; Liu, Zhenxing ; Ge, Rui ; Xiao, Qing ; Zhang, Yan ; Wang, Jianbo
刊名	angewandte chemie international edition
	2013
关键词	1,2-shift cyclization diazo compounds insertion hydrocarbons ASYMMETRIC ROSKAMP REACTION BETA-KETO-ESTERS AROMATIC-ALDEHYDES RING-EXPANSION ENANTIOSELECTIVE SYNTHESIS DIRECTED ORTHO POLYSUBSTITUTED NAPHTHOLS REGIOSPECIFIC SYNTHESIS TOSYLHYDRAZONE SALTS QUATERNARY CENTER
DOI	10.1002/anie.201209269
英文摘要	The different reactivity of two kinds of carbonyl groups in keto aldehyde substrates has been exploited for the synthesis of phenanthrols, naphthols, and their heteroatom-containing analogues. Key to this highly efficient and robust methodology is the catalyst-free intramolecular formal diazo carbon insertion of N-tosylhydrazones into keto C-C bonds.Copyright ? 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.; Chemistry, Multidisciplinary; SCI(E); PubMed; 15; ARTICLE; 9; 2543-2546; 52
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/190703]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xia, Ying,Qu, Peiyuan,Liu, Zhenxing,et al. Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C Bonds: A New Approach toward Phenanthrols and Naphthols[J]. angewandte chemie international edition,2013.
APA	Xia, Ying.,Qu, Peiyuan.,Liu, Zhenxing.,Ge, Rui.,Xiao, Qing.,...&Wang, Jianbo.(2013).Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C Bonds: A New Approach toward Phenanthrols and Naphthols.angewandte chemie international edition.
MLA	Xia, Ying,et al."Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C Bonds: A New Approach toward Phenanthrols and Naphthols".angewandte chemie international edition (2013).