Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile   Synthesis, Structural Characterization, and Reaction Chemistry

doi:10.1021/ja4114243

CORC > 北京大学 > 化学与分子工程学院

	Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry
	Geng, Weizhi ; Wei, Junnian ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	journal of the american chemical society
	2014
关键词	ALL-CIS-OCTATETRAENES RAY CRYSTAL-STRUCTURE SOLID-STATE PHOTOLUMINESCENCE PROPERTIES MOLECULAR-STRUCTURE COPPER COMPLEXES LITHIUM ZIRCONACYCLOPENTADIENES DERIVATIVES
DOI	10.1021/ja4114243
英文摘要	Four types of alkenyl organocopper(I) aggregates linked by 1,3-butadienyl and/or 1,3,5,7-octatetraenyl moieties were selectively realized in good isolated yields. All these organocopper(I) aggregates were structurally characterized by single-crystal X-ray structural analysis. These unprecedented aggregates, stabilized by multiple Cu-Cu interactions and the conjugated 1,3-butadienyl or 1,3,5,7-octatetraenyl bridges, could undergo controlled structural transformations. The 1,4-dicopper 1,3-butadienyl aggregate 3 could be efficiently transformed to aggregate 2, while LiI could disaggregate the 1,3-butadienyl-1,3,5,7-octatetraenyl aggregate 4 to 1,3,5,7-octatetraenyl aggregate 5 and 1,3-butadienyl aggregate 2. Preliminary reaction chemistry and synthetic applications of these organocopper(I) aggregates were also investigated.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000330018600018&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); PubMed; 13; ARTICLE; zfxi@pku.edu.cn; 2; 610-613; 136
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/190060]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Geng, Weizhi,Wei, Junnian,Zhang, Wen-Xiong,et al. Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry[J]. journal of the american chemical society,2014.
APA	Geng, Weizhi,Wei, Junnian,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry.journal of the american chemical society.
MLA	Geng, Weizhi,et al."Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry".journal of the american chemical society (2014).