Barium Dibenzopentalenide as a Main-Group Metal eta(8) Complex: Facile Synthesis from 1,4-Dilithio-1,3-butadienes and Ba[N(SiMe3)(2)](2), Structural Characterization, and Reaction Chemistry | |
Li, Heng ; Wei, Baosheng ; Xu, Ling ; Zhang, Wen-Xiong ; Xi, Zhenfeng | |
刊名 | angewandte chemie international edition |
2013 | |
关键词 | barium coordination modes dibenzopentalene pentalene ALL-CIS-OCTATETRAENES MOLECULAR-STRUCTURE PENTALENE COMPLEXES CYCLOPENTADIENE DERIVATIVES ORGANOMETALLIC CHEMISTRY SKELETAL REARRANGEMENT SANDWICH COMPLEXES AROMATIC SYSTEMS DIANION ACTIVATION |
DOI | 10.1002/anie.201305254 |
英文摘要 | Transmetalation of 1,4-dilithio-1,3-butadienes with Ba[N(SiMe 3)2]2 gave barium dibenzopentalenides, which were structurally characterized by single-crystal X-ray analysis. A preliminary study of the reaction chemistry of thus obtained barium dibenzopentalenides demonstrated that synthetically useful applications can be expected. Copyright ? 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000325157600031&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 16; ARTICLE; 41; 10822-10825; 52 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/189689] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Heng,Wei, Baosheng,Xu, Ling,et al. Barium Dibenzopentalenide as a Main-Group Metal eta(8) Complex: Facile Synthesis from 1,4-Dilithio-1,3-butadienes and Ba[N(SiMe3)(2)](2), Structural Characterization, and Reaction Chemistry[J]. angewandte chemie international edition,2013. |
APA | Li, Heng,Wei, Baosheng,Xu, Ling,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2013).Barium Dibenzopentalenide as a Main-Group Metal eta(8) Complex: Facile Synthesis from 1,4-Dilithio-1,3-butadienes and Ba[N(SiMe3)(2)](2), Structural Characterization, and Reaction Chemistry.angewandte chemie international edition. |
MLA | Li, Heng,et al."Barium Dibenzopentalenide as a Main-Group Metal eta(8) Complex: Facile Synthesis from 1,4-Dilithio-1,3-butadienes and Ba[N(SiMe3)(2)](2), Structural Characterization, and Reaction Chemistry".angewandte chemie international edition (2013). |
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