Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives | |
Zhang, Shaoguang ; Zhan, Ming ; Zhang, Wen-Xiong ; Xi, Zhenfeng | |
刊名 | chemistry a european journal
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2014 | |
关键词 | bipyrrolines diastereoselectivity Lewis acids nucleophiles ring opening NITROGEN-CONTAINING HETEROCYCLES CATALYTIC ASYMMETRIC-SYNTHESIS LEWIS-ACID CYCLOADDITION REACTIONS BISHOMOAROMATIC SEMIBULLVALENES DIMETHYLOXOSULFONIUM METHYLIDE STRUCTURAL-CHARACTERIZATION STEREOSELECTIVE-SYNTHESIS AZIRIDINES HOMOAROMATICITY |
DOI | 10.1002/chem.201402911 |
英文摘要 | Nucleophilic ring-opening reactions of 2,6-diazasemibullvalenes (NSBVs) were investigated. Different types of nucleophile (alcohols, phenols, thiols, carboxylic acids, water, enols, amines, indoles, metal-halide salts, sodium azide, organozinc compounds, lithium alkynethiolate, and sulfoxonium ylides) were used to afford diverse functionalized Delta(1)-bipyrroline derivatives in good yields with high regio- and diastereoselectivity. Most of the reactions featured milder conditions and higher reactivity relative to those for common aziridine derivatives, probably because of the rigid ring system and substitution patterns of NSBVs.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000340176600038&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 4; ARTICLE; zfxi@pku.edu.cn; 31; 9744-9752; 20 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/189326] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhang, Shaoguang,Zhan, Ming,Zhang, Wen-Xiong,et al. Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives[J]. chemistry a european journal,2014. |
APA | Zhang, Shaoguang,Zhan, Ming,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives.chemistry a european journal. |
MLA | Zhang, Shaoguang,et al."Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives".chemistry a european journal (2014). |
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