Diastereoselective Nucleophilic Ring-Opening Reactions of   2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized   Delta(1)-Bipyrroline Derivatives

doi:10.1002/chem.201402911

CORC > 北京大学 > 化学与分子工程学院

	Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives
	Zhang, Shaoguang ; Zhan, Ming ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	chemistry a european journal
	2014
关键词	bipyrrolines diastereoselectivity Lewis acids nucleophiles ring opening NITROGEN-CONTAINING HETEROCYCLES CATALYTIC ASYMMETRIC-SYNTHESIS LEWIS-ACID CYCLOADDITION REACTIONS BISHOMOAROMATIC SEMIBULLVALENES DIMETHYLOXOSULFONIUM METHYLIDE STRUCTURAL-CHARACTERIZATION STEREOSELECTIVE-SYNTHESIS AZIRIDINES HOMOAROMATICITY
DOI	10.1002/chem.201402911
英文摘要	Nucleophilic ring-opening reactions of 2,6-diazasemibullvalenes (NSBVs) were investigated. Different types of nucleophile (alcohols, phenols, thiols, carboxylic acids, water, enols, amines, indoles, metal-halide salts, sodium azide, organozinc compounds, lithium alkynethiolate, and sulfoxonium ylides) were used to afford diverse functionalized Delta(1)-bipyrroline derivatives in good yields with high regio- and diastereoselectivity. Most of the reactions featured milder conditions and higher reactivity relative to those for common aziridine derivatives, probably because of the rigid ring system and substitution patterns of NSBVs.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000340176600038&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 4; ARTICLE; zfxi@pku.edu.cn; 31; 9744-9752; 20
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/189326]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Shaoguang,Zhan, Ming,Zhang, Wen-Xiong,et al. Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives[J]. chemistry a european journal,2014.
APA	Zhang, Shaoguang,Zhan, Ming,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives.chemistry a european journal.
MLA	Zhang, Shaoguang,et al."Diastereoselective Nucleophilic Ring-Opening Reactions of 2,6-Diazasemibullvalenes for the Synthesis of Diverse Functionalized Delta(1)-Bipyrroline Derivatives".chemistry a european journal (2014).