Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and   lndanones via Rhodium-Catalyzed Tandem Reactions of   2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones

doi:10.1021/ol502617m

CORC > 北京大学 > 化学与分子工程学院

	Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and lndanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones
	Shen, Hongjuan ; Fu, Junkai ; Gong, Jianxian ; Yang, Zhen
刊名	organic letters
	2014
关键词	CARBON TRIPLE BOND AZAVINYL CARBENES TERMINAL ALKYNES STEREOSELECTIVE-SYNTHESIS SPIROBENZYLISOQUINOLINE ALKALOIDS DIASTEREOSELECTIVE SYNTHESIS INTRAMOLECULAR CYCLIZATION ORTHO-ALKYNYLBENZALDEHYDES ENANTIOSELECTIVE SYNTHESIS O-ALKYNYLBENZALDEHYDES
DOI	10.1021/ol502617m
英文摘要	Two novel rhodium(II)-catalyzed tandem reactions were developed for the synthesis of dihydroisobenzofuran and indanone derivatives from 2-triazole-benzaldehydes and 2-triazole-alkylaryl ketones. Dihydroisobenzofuran derivatives were obtained in good yields with high regioselectivities when alcohols were used as nuclophiles in these reactions, whereas the replacement of the alcohol with water resulted in the diastereoselective formation of highly functionalized indanone derivatives.; Chemistry, Organic; SCI(E); PubMed; 4; ARTICLE; gongjx@pku.edu.cn; zyang@pku.edu.cn; 21; 5588-5591; 16
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/188895]
专题	化学与分子工程学院生命科学学院
推荐引用方式 GB/T 7714	Shen, Hongjuan,Fu, Junkai,Gong, Jianxian,et al. Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and lndanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones[J]. organic letters,2014.
APA	Shen, Hongjuan,Fu, Junkai,Gong, Jianxian,&Yang, Zhen.(2014).Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and lndanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones.organic letters.
MLA	Shen, Hongjuan,et al."Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and lndanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones".organic letters (2014).