Efficient Synthesis of Aza-triquinacene Derivatives via Cycloaddition of 2,6-Diazasemibullvalenes with Nitroso Compounds | |
Zhan, Ming ; Zhang, Shaoguang ; Huang, Zhe ; Xi, Zhenfeng | |
刊名 | chemistry an asian journal
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2015 | |
关键词 | aza-triquinacene cycloaddition diazasemibullvalene nitroso compound (1)-bipyrroline RING-OPENING REACTIONS N-ALKENYL AZIRIDINES STRUCTURAL-CHARACTERIZATION HYDROGENATION PRODUCTS TRIBUTYLPHOSPHINE HOMOAROMATICITY BIOSYNTHESIS HETEROCYCLES NITRILES |
DOI | 10.1002/asia.201403030 |
英文摘要 | The reaction between 2,6-diazasemibullvalenes and nitroso compounds was investigated. Aza-triquinacene derivatives of interesting structural and synthetic chemistry were generated highly selectively in good to excellent isolated yields. This reaction, which was rarely found between common aziridine derivatives and nitroso compounds, could be attributed to the rigid polycyclic ring system and the substitution patterns of 2,6-diazasemibullvalenes. (1)-Bipyrroline derivatives were formed in excellent yields when these aza-triquinacene derivatives were treated with SmI2.; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 0; ARTICLE; zfxi@pku.edu.cn; 4,SI; 862-864; 10 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/188537] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhan, Ming,Zhang, Shaoguang,Huang, Zhe,et al. Efficient Synthesis of Aza-triquinacene Derivatives via Cycloaddition of 2,6-Diazasemibullvalenes with Nitroso Compounds[J]. chemistry an asian journal,2015. |
APA | Zhan, Ming,Zhang, Shaoguang,Huang, Zhe,&Xi, Zhenfeng.(2015).Efficient Synthesis of Aza-triquinacene Derivatives via Cycloaddition of 2,6-Diazasemibullvalenes with Nitroso Compounds.chemistry an asian journal. |
MLA | Zhan, Ming,et al."Efficient Synthesis of Aza-triquinacene Derivatives via Cycloaddition of 2,6-Diazasemibullvalenes with Nitroso Compounds".chemistry an asian journal (2015). |
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