Synthesis of alpha,alpha,alpha &apos; ,alpha   &apos;-Tetrachloro-Delta(1)-bipyrrolines and   4,8-Dichloro-2,6-diazasemibuvallenes

doi:10.1021/acs.orglett.5b00136

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes
	Zhan, Ming ; Zhang, Shaoguang ; Huang, Zhe ; Xi, Zhenfeng
刊名	organic letters
	2015
关键词	COPE REARRANGEMENT BISHOMOAROMATIC SEMIBULLVALENES STRUCTURAL-CHARACTERIZATION 2,6-DIAZASEMIBULLVALENES CHEMISTRY HOMOAROMATICITY STABILIZATION BARBARALANES SPECTROSCOPY DERIVATIVES
DOI	10.1021/acs.orglett.5b00136
英文摘要	A series of 4,8-dichloro-2,6-diazasemibullvalenes were synthesized and isolated from the reaction of alpha,alpha,alpha' ,alpha'-tetrachloro-Delta(1)-bipyrrolines with lithium via C-N bond formation., All those dichlorodiazaseniibullvalene derivatives demonstrated extremely rapid aza=Cope rearrangement in solution. An unprecedented skeletal rearrangement of 4,8-dichloro-2,6-diazasemibullvalene derivatives took place, resulting in the formation of a new bipyrroline skeleton.; Chemistry, Organic; SCI(E); PubMed; 0; ARTICLE; zfxi@pku.edu.cn; 4; 1026-1029; 17
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/188323]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhan, Ming,Zhang, Shaoguang,Huang, Zhe,et al. Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes[J]. organic letters,2015.
APA	Zhan, Ming,Zhang, Shaoguang,Huang, Zhe,&Xi, Zhenfeng.(2015).Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes.organic letters.
MLA	Zhan, Ming,et al."Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes".organic letters (2015).