Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes | |
Zhan, Ming ; Zhang, Shaoguang ; Huang, Zhe ; Xi, Zhenfeng | |
刊名 | organic letters
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2015 | |
关键词 | COPE REARRANGEMENT BISHOMOAROMATIC SEMIBULLVALENES STRUCTURAL-CHARACTERIZATION 2,6-DIAZASEMIBULLVALENES CHEMISTRY HOMOAROMATICITY STABILIZATION BARBARALANES SPECTROSCOPY DERIVATIVES |
DOI | 10.1021/acs.orglett.5b00136 |
英文摘要 | A series of 4,8-dichloro-2,6-diazasemibullvalenes were synthesized and isolated from the reaction of alpha,alpha,alpha' ,alpha'-tetrachloro-Delta(1)-bipyrrolines with lithium via C-N bond formation., All those dichlorodiazaseniibullvalene derivatives demonstrated extremely rapid aza=Cope rearrangement in solution. An unprecedented skeletal rearrangement of 4,8-dichloro-2,6-diazasemibullvalene derivatives took place, resulting in the formation of a new bipyrroline skeleton.; Chemistry, Organic; SCI(E); PubMed; 0; ARTICLE; zfxi@pku.edu.cn; 4; 1026-1029; 17 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/188323] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhan, Ming,Zhang, Shaoguang,Huang, Zhe,et al. Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes[J]. organic letters,2015. |
APA | Zhan, Ming,Zhang, Shaoguang,Huang, Zhe,&Xi, Zhenfeng.(2015).Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes.organic letters. |
MLA | Zhan, Ming,et al."Synthesis of alpha,alpha,alpha ' ,alpha '-Tetrachloro-Delta(1)-bipyrrolines and 4,8-Dichloro-2,6-diazasemibuvallenes".organic letters (2015). |
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