Self-assembled two-dimensional nanoporous molecular arrays and photoinduced polymerization of 4-bromo-4 '-hydroxybiphenyl on Ag(111) | |
Shen, Qian ; He, Jing Hui ; Zhang, Jia Lin ; Wu, Kai ; Xu, Guo Qin ; Wee, Andrew Thye Shen ; Chen, Wei | |
刊名 | journal of chemical physics |
2015 | |
关键词 | SCANNING TUNNELING MICROSCOPE PUMP-PROBE SPECTROSCOPY 266 NM PHOTODISSOCIATION DYNAMICS HYBRID CHAINS SURFACE HALOGEN DICHLOROBENZENE |
DOI | 10.1063/1.4906116 |
英文摘要 | Self-assembled two-dimensional molecular arrays and photoinduced polymerization of 4-bromo4'-hydroxybiphenyl on Ag(111) were studied using low-temperature scanning tunneling microscopy combined with density functional theory calculations. Square-like self-assembled structures of 4-bromo-4'-hydroxybiphenyl stabilized by intermolecular hydrogen and halogen bonds were transformed into hexagonal nanopores of biphenyl biradicals by 266 nm UV laser irradiation at 80 K. The biradicals further coupled to each other and formed covalently linked polyphenylene polymer chains at room temperature. (C) 2015 AIP Publishing LLC.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000350978000003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Physics, Atomic, Molecular & Chemical; SCI(E); EI; PubMed; 2; ARTICLE; phycw@nus.edu.sg; 10; 101902; 142 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/188253] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Shen, Qian,He, Jing Hui,Zhang, Jia Lin,et al. Self-assembled two-dimensional nanoporous molecular arrays and photoinduced polymerization of 4-bromo-4 '-hydroxybiphenyl on Ag(111)[J]. journal of chemical physics,2015. |
APA | Shen, Qian.,He, Jing Hui.,Zhang, Jia Lin.,Wu, Kai.,Xu, Guo Qin.,...&Chen, Wei.(2015).Self-assembled two-dimensional nanoporous molecular arrays and photoinduced polymerization of 4-bromo-4 '-hydroxybiphenyl on Ag(111).journal of chemical physics. |
MLA | Shen, Qian,et al."Self-assembled two-dimensional nanoporous molecular arrays and photoinduced polymerization of 4-bromo-4 '-hydroxybiphenyl on Ag(111)".journal of chemical physics (2015). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论