Four thiocyanato-bridged cadmium(II) polymeric complexes based on open   chain diazine ligands

doi:10.1016/j.molstruc.2007.04.002

CORC > 北京大学 > 化学与分子工程学院

	Four thiocyanato-bridged cadmium(II) polymeric complexes based on open chain diazine ligands
	Yue, Yan-Feng ; Fang, Chen-Jie ; Gao, En-Qing ; He, Cheng ; Bai, Shi-Qiang ; Xu, Sheng ; Yan, Chun-Hua
刊名	分子结构杂志
	2008
关键词	Cd(II) complexes open chain diazine ligands crystal structures thiocyanate bridges three-dimensional (10,3)-b net MAGNETIC-PROPERTIES CRYSTAL-STRUCTURE SCHIFF-BASE SPONTANEOUS RESOLUTION COPPER(II) COMPLEXES WEAK FERROMAGNETISM DINUCLEAR COMPLEXES NICKEL(II) COMPLEX COORDINATION NI
DOI	10.1016/j.molstruc.2007.04.002
英文摘要	One 1 D and three 3D thiocyanate cadmium(II) polymeric complexes with a series of open chain diazine Schiff bases as auxiliary bridging ligands have been synthesized and crystallographically characterized. In the 1D complex [Cd(L-1)(mu(1,3)-NCS)(4)](n) (1, L-1 = 1-(2-pyridyl)-4-phenyl-1-amino-2,3-diaza-1,3-butadiene), cadmium(II) ions are interlinked by double mu-1,3 thiocyanate ligands resulting in a 1D chain running along a direction. The three 3D complexes are isostructural with general formula of [Cd-2(L2-4)(mu(1,3)-NCS)(2)](n) (2-4, respectively, L-2 = 1,4-bis(2-pyridyl)-1,4-diamino-2,3-diaza-1,3-butadiene, L-3 = 1,4-bis(2-pyridyl)-1-amino-2,3-diaza-1,3-butadiene, L-4 = 1,4-bis(2-pyridyl)-1-amino-4-methyl-2,3-diaza-1,3-butadiene). In the complexes of 2-4, the double mu-1,3 thiocyanate ligands form a chain and the chains are further interlinked by single diazine ligands into a three-dimensional (10,3)-b net with each cadmium ion as a node. (C) 2007 Elsevier B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000254765700013&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; SCI(E); EI; 4; ARTICLE; 1-3; 80-85; 875
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/151503]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yue, Yan-Feng,Fang, Chen-Jie,Gao, En-Qing,et al. Four thiocyanato-bridged cadmium(II) polymeric complexes based on open chain diazine ligands[J]. 分子结构杂志,2008.
APA	Yue, Yan-Feng.,Fang, Chen-Jie.,Gao, En-Qing.,He, Cheng.,Bai, Shi-Qiang.,...&Yan, Chun-Hua.(2008).Four thiocyanato-bridged cadmium(II) polymeric complexes based on open chain diazine ligands.分子结构杂志.
MLA	Yue, Yan-Feng,et al."Four thiocyanato-bridged cadmium(II) polymeric complexes based on open chain diazine ligands".分子结构杂志 (2008).