Room Temperature Ionic Liquids Assisted Green Synthesis of Nanocrystalline Porous SnO2 and Their Gas Sensor Behaviors | |
Li, Le-Le ; Zhang, Wei-Ming ; Yuan, Quan ; Li, Zhen-Xing ; Fang, Cheng-Jie ; Sun, Ling-Dong ; Wan, Li-Jun ; Yan, Chun-Hua | |
刊名 | crystal growth design
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2008 | |
关键词 | SENSING PROPERTIES MESOPOROUS SNO2 HYDROTHERMAL SYNTHESIS IONOTHERMAL SYNTHESIS NANOCASTING TECHNIQUE OXIDE NANOPARTICLES AMBIENT CONDITIONS TIO2 NANOCRYSTALS MOLECULAR-SIEVES FACILE SYNTHESIS |
DOI | 10.1021/cg800686w |
英文摘要 | Nanocrystalline porous tin dioxide (SnO2) materials have been obtained employing room temperature ionic liquids (1-hexadecyl-3-methylimidazolium bromide, C(16)MimBr) as a template via a green sol-gel method at ambient temperature followed by a suitable thermal treatment. These materials have been thoroughly characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, FTIR, and nitrogen adsorption-desorption. A careful tuning of heat-treatment procedures allowed the preparation of SnO2 functional materials with Brunauer-Emmett-Teller surface areas ranging from 38 to 140 m(2) g(-1), an average pore size between super-micropore (1-2 nm) and mesopore (10 nm) range, and a mean particle size from 3.0 to 10.0 nm. The applications in gas sensors for the nanostructures reveal that the obtained SnO2 Materials exhibit highly sensitive, fast-responding, reproducible, and size selective sensing behaviors. The sensor characteristics were discussed in relation to the architectures of the materials, which disclose that the gas-sensor properties are strongly structure-dependent.; Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary; SCI(E); 52; ARTICLE; 11; 4165-4172; 8 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/151457] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Le-Le,Zhang, Wei-Ming,Yuan, Quan,et al. Room Temperature Ionic Liquids Assisted Green Synthesis of Nanocrystalline Porous SnO2 and Their Gas Sensor Behaviors[J]. crystal growth design,2008. |
APA | Li, Le-Le.,Zhang, Wei-Ming.,Yuan, Quan.,Li, Zhen-Xing.,Fang, Cheng-Jie.,...&Yan, Chun-Hua.(2008).Room Temperature Ionic Liquids Assisted Green Synthesis of Nanocrystalline Porous SnO2 and Their Gas Sensor Behaviors.crystal growth design. |
MLA | Li, Le-Le,et al."Room Temperature Ionic Liquids Assisted Green Synthesis of Nanocrystalline Porous SnO2 and Their Gas Sensor Behaviors".crystal growth design (2008). |
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