Sensitized luminescence from lanthanides in d-f bimetallic complexes | |
Chen, Fang-Fang ; Chen, Zhu-Qi ; Bian, Zu-Qiang ; Huang, Chun-Hui | |
刊名 | coordination chemistry reviews
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2010 | |
关键词 | Bimetallic complexes Transition metals Lanthanides Red emission NIR emission NEAR-INFRARED LUMINESCENCE INTRAMOLECULAR ENERGY TRANSFER SCHIFF-BASE COMPLEXES ZN-ND COMPLEXES TERPYRIDYL-FUNCTIONALIZED ALKYNYL ANCILLARY OLIGOPYRIDINE LIGANDS VISIBLE-LIGHT SENSITIZATION TRANSITION-METAL COMPLEXES RARE-EARTH COMPLEXES PHOTOPHYSICAL PROPERTIES |
DOI | 10.1016/j.ccr.2009.12.028 |
英文摘要 | This article reviews progress in the research of transition metal-lanthanide (d-f) bimetallic complexes Through efficient energy transfer, sensitized luminescence of lanthanide ions from the visible range (Eu(III)) to the near-infrared region (Nd(III), Yb(III), Er(III) and Pr(III)) is obtained in these bimetallic assembles The d-block in d-f bimetallic complexes mainly contributes to the improvement of lanthanide emission efficiency and the extension of the excitation window for the lanthanide complexes. Examples are catalogued by various transition metals, such as Ru(II), Os(II) (Fe(II)), Pt(II) (Au(I)), Pd(II), Cr(III), Co(III), Zn(II) and Ir(III). The relevant synthetic procedures, crystal structures and photophysical properties of these d-f complexes are briefly described Additionally, the molecular properties responsible for the performance of certain d-f systems, such as energy levels, nuclear distances and coordination environments, will be discussed (C) 2009 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 92; REVIEW; 9-10,SI; 991-1010; 254 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/151197] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,et al. Sensitized luminescence from lanthanides in d-f bimetallic complexes[J]. coordination chemistry reviews,2010. |
APA | Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,&Huang, Chun-Hui.(2010).Sensitized luminescence from lanthanides in d-f bimetallic complexes.coordination chemistry reviews. |
MLA | Chen, Fang-Fang,et al."Sensitized luminescence from lanthanides in d-f bimetallic complexes".coordination chemistry reviews (2010). |
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