H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally   Four-Connected Borate Layers and InO6 Octahedra

doi:10.1002/ejic.200901078

CORC > 北京大学 > 化学与分子工程学院

	H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra
	Cong, Rihong ; Yang, Tao ; Li, Hongmei ; Liao, Fuhui ; Wang, Yingxia ; Lin, Jianhua
刊名	欧洲无机化学杂志
	2010
关键词	Borates Indium X-ray diffraction Network structures Hydrogen bonds FUNDAMENTAL BUILDING-BLOCKS SOLID-STATE NMR CRYSTAL-STRUCTURE STRUCTURAL SYSTEM HYDROGEN-BONDS SPECTROSCOPY CHEMISTRY CLASSIFICATION MINERALS ALKALINE
DOI	10.1002/ejic.200901078
英文摘要	H2InB5O10, a new hydrated indium pentaborate, was prepared by the boric acid flux method and characterized by IR, solid-state B-11 MAS NMR and H-1 CRAMPS NMR spectroscopy. Its structure was determined by powder X-ray diffraction and refined by Rietveld analysis. H2InB5O10 crystallizes in the monoclinic space group C2. The structure features a new 2D tetrahedrally four-connected borate network constructed from a new pentaborate fundamental building block, B5O14. The 2D borate network is formed by two 6(3) borate layers linked by additional BO4 groups in a spiro-5 mode and then combines with InO6 octahedra to give rise to the 3D structure of H2InB5O10. The strong hydrogen bonds that cross-link oxygen atoms of additional BO4 groups between the borate layers help to stabilize the borate network.; Chemistry, Inorganic & Nuclear; SCI(E); 6; ARTICLE; 11; 1703-1709
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/151174]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Cong, Rihong,Yang, Tao,Li, Hongmei,et al. H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra[J]. 欧洲无机化学杂志,2010.
APA	Cong, Rihong,Yang, Tao,Li, Hongmei,Liao, Fuhui,Wang, Yingxia,&Lin, Jianhua.(2010).H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra.欧洲无机化学杂志.
MLA	Cong, Rihong,et al."H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra".欧洲无机化学杂志 (2010).