A highly efficient Co (0) catalyst derived from metal-organic framework   for the hydrolysis of ammonia borane

doi:10.1016/j.ijhydene.2011.05.120

CORC > 北京大学 > 化学与分子工程学院

	A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane
	Song, Ping ; Li, Yaoqi ; Li, Wei ; He, Bei ; Yang, Junzhi ; Li, Xingguo
刊名	国际氢能杂志
	2011
关键词	Metal-organic frameworks Heterogeneous catalyst Ammonia borane Hydrolysis CHEMICAL HYDROGEN STORAGE ROOM-TEMPERATURE STABILIZED RUTHENIUM(0) NANOCLUSTERS CATALYST SHELL NANOPARTICLES ACTIVE CATALYSTS H-2 GENERATION DEHYDROGENATION NH3BH3 THERMOLYSIS
DOI	10.1016/j.ijhydene.2011.05.120
英文摘要	A Co (0) catalyst is synthesized by the reduction of a metal-organic framework (MOF) precursor Co(2)(bdc)(2)(dabco) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2] octane). The amorphous catalyst exhibits highly efficient activity in the hydrolysis of ammonia borane (AB). The dehydrogenation of a 0.32 M aqueous AB solution completes in 1.4 min under room temperature. The porous structure in the MOF is proposed to play a key role. The catalytic effective Co (0) sites are stabilized by the organic molecules, which used to coordinate to Co (II) in the MOP precursor. This work implies that MOFs, with their large surface area and ample pore structures, may serve as ideal precursors for highly efficient heterogeneous catalysts. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000295235200003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; Electrochemistry; Energy & Fuels; SCI(E); EI; 28; ARTICLE; 17; 10468-10473; 36
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/151028]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Song, Ping,Li, Yaoqi,Li, Wei,et al. A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane[J]. 国际氢能杂志,2011.
APA	Song, Ping,Li, Yaoqi,Li, Wei,He, Bei,Yang, Junzhi,&Li, Xingguo.(2011).A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane.国际氢能杂志.
MLA	Song, Ping,et al."A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane".国际氢能杂志 (2011).