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A new ionic liquid organic redox electrolyte for high-efficiency iodine-free dye-sensitized solar cells
Wu, Hongwei ; Lv, Zhibin ; Hou, Shaocong ; Cai, Xin ; Wang, Dan ; Kafafy, Hany ; Fu, Yongping ; Zhang, Chao ; Chu, Zengze ; Zou, Dechun
刊名电源杂志
2013
关键词Ionic liquid Dye-sensitized solar cells Organic redox Iodine-free Ink carbon TEMPERATURE MOLTEN-SALTS COUNTER ELECTRODE SOLVENT-FREE PERFORMANCE CARBON MEDIATOR RECOMBINATION CONVERSION SYSTEMS
DOI10.1016/j.jpowsour.2012.07.067
英文摘要A new ionic liquid (IL) 5-mercapto-1-methyltetrazole 1-methyl-3-propylimidazolium salt PMIT with di-5-(1-methyltetrazole) disulfide (T-2) as the organic reclox couple is adopted for application in IL dye-sensitized solar cells (DSSCs). Adopting ultralow-cost and superior catalytic ink carbon as the counter electrode (CE), the N719- and D102-sensitized devices show high efficiencies of 4.30% and 3.83% under 100 mW cm(-2) light illumination, respectively. Electrochemical studies provide insights on the mass-transfer and recombination kinetics of the electrolyte and electrochemical catalysis of the CE. The ink carbon CE exhibits more excellent catalytic activity than the Pt CE for the redox couple. These show an attractive prospect of carbon materials for application in DSSCs based on new iodine-free ionic liquid organic electrolyte. (C) 2012 Elsevier B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000310394800044&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Electrochemistry; Energy & Fuels; SCI(E); EI; 14; ARTICLE; 328-333; 221
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/150859]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Wu, Hongwei,Lv, Zhibin,Hou, Shaocong,et al. A new ionic liquid organic redox electrolyte for high-efficiency iodine-free dye-sensitized solar cells[J]. 电源杂志,2013.
APA Wu, Hongwei.,Lv, Zhibin.,Hou, Shaocong.,Cai, Xin.,Wang, Dan.,...&Zou, Dechun.(2013).A new ionic liquid organic redox electrolyte for high-efficiency iodine-free dye-sensitized solar cells.电源杂志.
MLA Wu, Hongwei,et al."A new ionic liquid organic redox electrolyte for high-efficiency iodine-free dye-sensitized solar cells".电源杂志 (2013).
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