Synthesis, crystal structure and visible light emission of a new   inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)]

doi:10.1016/j.molstruc.2013.05.023

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)]
	Luo, Wenjiao ; Wang, Yonggang ; Wen, Ting ; Zhang, Hao ; Lin, Xiaohuan ; Wang, Yingxia ; Liao, Fuhui ; Lin, Jianhua
刊名	分子结构杂志
	2013
关键词	Borate Crystal structure Hydrothermal Luminescence White-light-emission NONMETAL PENTABORATE UV ABSORPTION BORATE GD ALUMINOBORATE LUMINESCENCE CHEMISTRY FRAMEWORK LU LN
DOI	10.1016/j.molstruc.2013.05.023
英文摘要	A new organic-inorganic hybrid pentaborate [C6H14N][B5O6(OH)(4)] (1) has been synthesised hydrothermally in aqueous solution and characterised by single-crystal X-ray diffraction, FT-IR, DTA-TG and photoluminescence spectroscopy. It crystallizes in the monoclinic system, space group P2(1)/c, with the lattice constants of a = 9.463 (2) angstrom, b = 14.005 (3) angstrom, c = 10.642 (2) angstrom, and beta = 93.82(3)degrees. The structure consists of isolated [B5O6(OH)(4)](-) groups interlinked by protonated cyclohexylamine via hydrogen bonding. Blue photoluminescence of 1 is observed upon UV excitation, which can be further enhanced and modified to near-white emission by thermal treatment. The maximum emissions and peak shapes of 1-250 degrees C are also tunable with various excitation wavelengths in the region of 350-470 nm. This compound provides a novel example of organically templated borate materials potential for display and lighting applications. (c) 2013 Elsevier B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000323468500001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; SCI(E); 2; ARTICLE; 1-5; 1048
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150725]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Luo, Wenjiao,Wang, Yonggang,Wen, Ting,et al. Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)][J]. 分子结构杂志,2013.
APA	Luo, Wenjiao.,Wang, Yonggang.,Wen, Ting.,Zhang, Hao.,Lin, Xiaohuan.,...&Lin, Jianhua.(2013).Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)].分子结构杂志.
MLA	Luo, Wenjiao,et al."Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)]".分子结构杂志 (2013).