Synthesis, Langmuir-Blodgett deposition and optical characterization of   a 4-acetalphenyl-substituted C-60-pyrrolidine derivative C-60(C12H17NO2)

doi:10.1039/a608570i

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, Langmuir-Blodgett deposition and optical characterization of a 4-acetalphenyl-substituted C-60-pyrrolidine derivative C-60(C12H17NO2)
	Zhou, DJ ; Ashwell, GJ ; Rajan, R ; Gan, LB ; Luo, CP ; Huang, CH
刊名	journal of the chemical society faraday transactions
	1997
关键词	AIR-WATER-INTERFACE 2ND-HARMONIC GENERATION FILMS C-60 C60 FULLERENES BUCKMINSTERFULLERENE FULLEROPYRROLIDINES MICROSCOPY CHEMISTRY
DOI	10.1039/a608570i
英文摘要	A new 4-acetalphenyl-substituted C-60-pyrrolidine derivative, C-60(C12H17NO2) (1), has been prepared and its Langmuir films, with and without 22-tricosenoic acid [CH2=CH-(CH2)(20)CO2H(TA)], at the air/water interface have been investigated. Pure 1 forms monolayers more easily than the parent molecule, C-60, and can be transferred onto solid substrates to form Langmuir-Blodgett (LB) films. The mixed Langmuir films of 1 and TA were transferred onto hydrophilically pretreated quartz, glass substrates and silicon wafers. Reflectometric measurement of a 63-layer 1:2 mixed film on a silicon wafer using an He-Ne laser (lambda = 632.8 nm) provided a film thickness and refractive index of 171 nm and 1.73, respectively. Weak second harmonic generation (SHG) from LB monolayers of pure 1 and 1:2 and 1:4 mixed LB monolayer films of 1 and TA was observed. The second-order susceptibilities, chi(pp)((2)), Were evaluated to be in the range (4-6) x 10(-9) esu.; Chemistry, Physical; Physics, Atomic, Molecular & Chemical; SCI(E); 15; ARTICLE; 11; 2077-2081; 93
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150701]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhou, DJ,Ashwell, GJ,Rajan, R,et al. Synthesis, Langmuir-Blodgett deposition and optical characterization of a 4-acetalphenyl-substituted C-60-pyrrolidine derivative C-60(C12H17NO2)[J]. journal of the chemical society faraday transactions,1997.
APA	Zhou, DJ,Ashwell, GJ,Rajan, R,Gan, LB,Luo, CP,&Huang, CH.(1997).Synthesis, Langmuir-Blodgett deposition and optical characterization of a 4-acetalphenyl-substituted C-60-pyrrolidine derivative C-60(C12H17NO2).journal of the chemical society faraday transactions.
MLA	Zhou, DJ,et al."Synthesis, Langmuir-Blodgett deposition and optical characterization of a 4-acetalphenyl-substituted C-60-pyrrolidine derivative C-60(C12H17NO2)".journal of the chemical society faraday transactions (1997).