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Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension
Chen, Huhe ; Guo, Zhengduo ; Yu, Fangting ; Qi, Jian ; Zhang, Li ; Zhou, Yong ; Yang, Zhanlan ; Xu, Yizhuang ; Wu, Jinguang ; Xu, Guangxian
刊名胶体与界面科学杂志
2008
关键词Mixed micelle Vesicle Structural transition BILE-SALT-LECITHIN PHOSPHOLIPID VESICLE AGGREGATION BILIARY LIPID SYSTEMS MIXED MICELLES CHOLESTEROL CARRIERS MONO-VALENT METAL IONS SCATTERING CALCIUM TRANSITION
DOI10.1016/j.jcis.2008.09.011
英文摘要In this study, the influence of La3+ on the mixed egg-yolk phosphatidylcholine (EYPC)-sodium taurocholate TC) aggregates was investigated by using turbidity, quasi-elastic light-scattering (QELS) technique, Fourier transform infrared (FTIR) spectroscopy, and transmission electron microscopy (TEM). La3+ ions exert different effects on different EYPC-TC aggregates. The EYPC-TC mixed spheroidal micelles are stable in the presence of La3+ ions. The EYPC-TC vesicles are aggregated by the interaction of La3+ with the EYPC phosphate group. Particularly, La3+ causes structural transition of the EYPC-TC mixed disk micelles by changing the colloidal properties of TC. This process includes two steps, destruction of mixed disk micelles and formation of mixed spheroidal micelle. Several intermediate structures such as multi-lamellar vesicles and cylindrical micelles were observed during the transition. The experimental data and analysis in the current study suggest that metal ion is one of the important factors to control the structure of the EYPC-TC self-assemblies. And the possible influence of metal ions on the properties of bile biocolloid has been discussed. (C) 2008 Elsevier Inc. All rights reserved.; Chemistry, Physical; SCI(E); EI; PubMed; 2; ARTICLE; 1; 158-165; 328
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/150194]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Chen, Huhe,Guo, Zhengduo,Yu, Fangting,et al. Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension[J]. 胶体与界面科学杂志,2008.
APA Chen, Huhe.,Guo, Zhengduo.,Yu, Fangting.,Qi, Jian.,Zhang, Li.,...&Xu, Guangxian.(2008).Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension.胶体与界面科学杂志.
MLA Chen, Huhe,et al."Influence of La3+ ions on the egg-yolk phosphatidylcholine and sodium taurocholate self-assemblies in aqueous suspension".胶体与界面科学杂志 (2008).
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