Reactivity and kinetic-mechanistic studies of regioselective reactions   of rhodium porphyrins with unactivated olefins in water that form   beta-hydroxyalkyl complexes and conversion to ketones and epoxides

doi:10.1039/b912219b

CORC > 北京大学 > 化学与分子工程学院

	Reactivity and kinetic-mechanistic studies of regioselective reactions of rhodium porphyrins with unactivated olefins in water that form beta-hydroxyalkyl complexes and conversion to ketones and epoxides
	Zhang, Jiadi ; Wayland, Bradford B. ; Yun, Lin ; Li, Shan ; Fu, Xuefeng
刊名	dalton transactions
	2010
关键词	ANTI-MARKOVNIKOV HYDROAMINATION AEROBIC OXIDATION INTRAMOLECULAR HYDROAMINATION EQUILIBRIUM THERMODYNAMICS CATALYTIC CONVERSIONS REDUCTIVE-ELIMINATION ORGANIC-CHEMICALS MOLECULAR-OXYGEN BOND FORMATION RH-OH
DOI	10.1039/b912219b
英文摘要	This article reports on the selective oxidation of unactivated alkenes to ketones and epoxides through the intermediacy of beta-hydroxyalkyl rhodium porphyrin complexes which are formed by reactions of terminal alkenes with tetra(p-sulfonatophenyl)porphyrin rhodium(III) complex. The beta-hydroxyalkyl rhodium porphyrin complexes in water undergo beta-C-H elimination to produce ketones in aqueous pH 9.0 solutions and O-H deprotonation in KOH/DMSO solutions resulting in the rapid and quantitative intramolecular nucleophilic displacement to form 1,2-epoxyalkanes.; Chemistry, Inorganic & Nuclear; SCI(E); EI; PubMed; 11; ARTICLE; 2; 477-483; 39
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150152]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Jiadi,Wayland, Bradford B.,Yun, Lin,et al. Reactivity and kinetic-mechanistic studies of regioselective reactions of rhodium porphyrins with unactivated olefins in water that form beta-hydroxyalkyl complexes and conversion to ketones and epoxides[J]. dalton transactions,2010.
APA	Zhang, Jiadi,Wayland, Bradford B.,Yun, Lin,Li, Shan,&Fu, Xuefeng.(2010).Reactivity and kinetic-mechanistic studies of regioselective reactions of rhodium porphyrins with unactivated olefins in water that form beta-hydroxyalkyl complexes and conversion to ketones and epoxides.dalton transactions.
MLA	Zhang, Jiadi,et al."Reactivity and kinetic-mechanistic studies of regioselective reactions of rhodium porphyrins with unactivated olefins in water that form beta-hydroxyalkyl complexes and conversion to ketones and epoxides".dalton transactions (2010).