Synthesis, characteristics and photoluminescent properties of novel   Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a   bridging ligand

doi:10.1039/c0dt01592j

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand
	Lian, Ping ; Wei, Huibo ; Zheng, Chen ; Nie, Yifan ; Bian, Jiang ; Bian, Zuqiang ; Huang, Chunhui
刊名	dalton transactions
	2011
关键词	INTRAMOLECULAR ENERGY-TRANSFER LIGHT-EMITTING-DIODES IRIDIUM COMPLEXES LANTHANIDE COMPLEXES EUROPIUM EMISSION LUMINESCENCE EFFICIENT DEVICES ELECTROLUMINESCENCE
DOI	10.1039/c0dt01592j
英文摘要	Two novel iridium(III) complexes, [Ir(dfppy)(2)(pmc)] and [Ir(ppy)(2)(pmc)] (dfppy = 2-(4', 6'-difluoro-phenyl) pyridine, ppy = 1-phenyl-pyridine), were designed and synthesized using 2- carboxyl-pyrimidine (Hpmc) as an ancillary ligand. Single crystals were obtained and characterized by single crystal X-ray diffraction. The tetrametallic complexes {[((CN)-N-boolean AND)(2)Ir(mu-pmc)](3)EuCl3} ((CN)-N-boolean AND = dfppy, ppy) were synthesized using the iridium(III) complexes as "ligands". Photophysical and theoretical studies indicate that [Ir(dfppy) 2(pmc)] is more suitable for sensitizing the emission of Eu(III) ions than [Ir(ppy)(2)(pmc)].; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000290161900011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); EI; PubMed; 13; ARTICLE; 20; 5476-5482; 40
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150020]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lian, Ping,Wei, Huibo,Zheng, Chen,et al. Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand[J]. dalton transactions,2011.
APA	Lian, Ping.,Wei, Huibo.,Zheng, Chen.,Nie, Yifan.,Bian, Jiang.,...&Huang, Chunhui.(2011).Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand.dalton transactions.
MLA	Lian, Ping,et al."Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand".dalton transactions (2011).