Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes:   Indenone Synthesis through Sequential C-H and C-N Cleavage

doi:10.1002/anie.201200271

CORC > 北京大学 > 化学与分子工程学院

	Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential C-H and C-N Cleavage
	Li, Bi-Jie ; Wang, Hao-Yuan ; Zhu, Qi-Lei ; Shi, Zhang-Jie
刊名	angewandte chemie international edition
	2012
关键词	annulation C?H activation heterocycles rhodium synthetic methods CARBONYLATIVE CYCLIZATION REACTIONS CARBON-HYDROGEN BONDS DIRECT ARYLATION ARYL-KETONES NUCLEOPHILIC-SUBSTITUTION UNSATURATED MOLECULES ASYMMETRIC-SYNTHESIS AROMATIC KETIMINES ORGANIC-SYNTHESIS DIRECTING GROUP
DOI	10.1002/anie.201200271
英文摘要	Doubled up: a rhodium(III)/copper(II) system co-catalyzes the annulation of benzimides with internal alkynes for the synthesis of indenones (see scheme; Cp*=C(5) Me(5)). The reaction involves an uncommon nucleophilic addition of a transition-metal-carbon bond to an imide moiety. This novel reaction provides a facile route to synthesize indenones from readily available benzimides and internal alkynes.Copyright ? 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.; Chemistry, Multidisciplinary; SCI(E); PubMed; 116; ARTICLE; 16; 3948-3952; 51
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/149908]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, Bi-Jie,Wang, Hao-Yuan,Zhu, Qi-Lei,et al. Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential C-H and C-N Cleavage[J]. angewandte chemie international edition,2012.
APA	Li, Bi-Jie,Wang, Hao-Yuan,Zhu, Qi-Lei,&Shi, Zhang-Jie.(2012).Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential C-H and C-N Cleavage.angewandte chemie international edition.
MLA	Li, Bi-Jie,et al."Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential C-H and C-N Cleavage".angewandte chemie international edition (2012).