Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride   Intermediates

doi:10.1002/anie.201208364

CORC > 北京大学 > 化学与分子工程学院

	Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates
	Lv, Hongbin ; Cai, Yuan-Bo ; Zhang, Jun-Long
刊名	angewandte chemie international edition
	2013
关键词	C-F activation copper fluorine homogeneous catalysis hydrides C-F BOND CARBON-FLUORINE BONDS METAL-COMPLEXES ASYMMETRIC HYDROSILYLATIONS CONJUGATE REDUCTIONS ACTIVATION FLUOROCARBONS RHODIUM PENTAFLUOROPYRIDINE CP-ASTERISK-2ZRH2
DOI	10.1002/anie.201208364
英文摘要	Breaking bad: Efficient copper-catalyzed C-F bond activation has been achieved by replacing fluorine with hydrogen. A copper hydride is proposed as the active intermediate, which proceeds through a nucleophilic attack on the fluorocarbon, as determined by experimental and theoretical results (see structure; C gray, H white, Cu light red, F light blue; distances in A). ? 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000316340700026&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 29; ARTICLE; 11; 3203-3207; 52
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/149823]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lv, Hongbin,Cai, Yuan-Bo,Zhang, Jun-Long. Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates[J]. angewandte chemie international edition,2013.
APA	Lv, Hongbin,Cai, Yuan-Bo,&Zhang, Jun-Long.(2013).Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates.angewandte chemie international edition.
MLA	Lv, Hongbin,et al."Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates".angewandte chemie international edition (2013).