Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes   Catalyzed by [RhCl(CO)(2)](2)

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	Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)(2)](2)
	Yu, Mengmeng ; Jing, Huize ; Fu, Xuefeng
刊名	inorganic chemistry
	2013
关键词	H BOND ACTIVATION RUTHENIUM COMPLEXES SIGMA-COMPLEXES SILYL ETHERS OXIDATION ALCOHOLYSIS ORGANOSILANES HYDROSILANES ROUTE DIPHENYLSILANE
DOI	10.1021/ic402022v
英文摘要	Catalytic hydrolysis of silanes mediated by chlorodicarbonylrhodium(I) dimer [RhCl(CO)(2)](2) to produce silanols and dihydrogen efficiently under mild conditions is reported. Second-order kinetics and activation parameters are determined by monitoring the rate of dihydrogen evolution. The mixing of [RhCl(CO)(2)](2) and HSiCl3 results in rapid formation of a rhodium silane a complex.; Chemistry, Inorganic & Nuclear; SCI(E); PubMed; 5; ARTICLE; 19; 10741-10743; 52
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/149741]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yu, Mengmeng,Jing, Huize,Fu, Xuefeng. Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)(2)](2)[J]. inorganic chemistry,2013.
APA	Yu, Mengmeng,Jing, Huize,&Fu, Xuefeng.(2013).Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)(2)](2).inorganic chemistry.
MLA	Yu, Mengmeng,et al."Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)(2)](2)".inorganic chemistry (2013).