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	聚(对乙烯基苯酚)的合成及其与重氮树脂的氢键自组装研究; Synthesis of poly(4-vinyl phenol)and its self-assembly with diazoresin via H-bond
	曹廷炳 ; 杨朝辉 ; 陈金玉 ; 曹维孝
	2001
关键词	聚(对乙烯基苯酚) 重氮树脂 氢键 自组装 poly(4-vinyl phenol) diazoresin H-bond self-assembly
英文摘要	Poly(4\|vinyl phenol) (PVPh) was synthesized from anisaldehyde via Perkin Doebner and decarboxyl reactions to form 4 methoxy styrene.It was then polymerized by free radical polymerization following dealkylation to form PVPh.A kind of stable multilayer utra thin film was successfully fabricated...; Poly(4-vinyl phenol) (PVPh) was synthesized from anisaldehyde via Perkin-Doebner and decarboxyl reactions to form 4-methoxy styrene. It was then polymerized by free-radical polymerization following dealkylation to form PVPh. A kind of stable multilayer utra-thin film was successfully fabricated via self-assembly technique from PVPh and diazoresin (DR) followed by UV irradiation. The driving force of self-assembly was confirmed to be the hydrogen bonding attraction from diazonium group(-N-2(+)) of DR and phenolic hydroxy group (-Ph-OH) of PVPh. The film becomes very stable towards polar solvents after UV irradiation and it is believed that the H-bonds between the layers of the film converts to covalent bonds following the decomposition of -N-2(+) groups when the multilayer film underwent UV irradiation.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000171044400031&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科学引文数据库(CSCD); 5; 02; 274-276
语种	中文
出处	知网 ; 万方 ; SCI
出版者	高分子学报
内容类型	其他
源URL	[http://hdl.handle.net/20.500.11897/80347]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	曹廷炳,杨朝辉,陈金玉,等. 聚(对乙烯基苯酚)的合成及其与重氮树脂的氢键自组装研究, Synthesis of poly(4-vinyl phenol)and its self-assembly with diazoresin via H-bond. 2001-01-01.

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