聚丙烯酸[2,5-双(对甲氧基苯甲酰氧基)苄酯]及聚甲基丙烯酸[2,5-双(对甲氧基苯甲酰氧基)苄酯]的合成; Synthesis of poly-[2,5-bis(4 '-methoxybenzoyloxy)benzyl acrylate] and poly-[2,5-bis(4 '-methoxybenzoyloxy)benzyl methacrylate] | |
糜七定 ; 宛新华 ; 周其凤 | |
2000 | |
关键词 | 聚丙烯酸[2 5-双(对甲氧基苯甲酰氧基)苄酯] 聚甲基丙烯酸[2 5一双(对甲氧基苯甲酰氧基)苄酯] “甲壳型”液晶高分子 poly-[2,5-bis(4 &apos poly-[2,5-bis(4 &apos methacrylate] mesogen-jacketed liquid crystalline polymers -methoxybenzoyloxy)benzyl acrylate] -methoxybenzoyloxy)benzyl |
英文摘要 | Two monomers of 2, 5-bis (4'-methoxybenzoyloxy) benzyl acrylate and 2, 5-bis (4'-methoxy- benzoyloxy)benzyl methacrylate and their corresponding polymers were successfully synthesized. The mesomorphic behavior of both polymers was examined using differential scanning calorimetry(DSC) and polarized...; Two monomers of 2,5-bis(4'-methoxybenzoyloxy) benzyl acrylate and 2,5-bis(4'-methoxybenzoyloxy)benzyl methacrylate and their corresponding polymers were successfully synthesized. The mesomorphic behavior of both polymers was examined using differential scanning calorimetry(DSC) and polarized optical microscopy(POM). It was found that both polymers are noncrystalline with a glass transition temperature of 73. 1 degrees C for poly-[2,5-bis(4'-methoxybenzoyloxy) benzyl acrylate] and 120. 3 degrees C for poly-[2, 5-bis ( 4'-methoxybenzoyloxy) benzyl methacrylate], above which liquid crystalline state is formed. The clearing temperature of the former is 178. 3 degrees C and that of the latter is 172. 8 degrees C.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000087161200043&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科学引文数据库(CSCD); 1; 05; 822-824; 21 |
语种 | 中文 |
出处 | 知网 ; 万方 ; SCI |
出版者 | 高等学校化学学报 |
内容类型 | 其他 |
源URL | [http://hdl.handle.net/20.500.11897/78515] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | 糜七定,宛新华,周其凤. 聚丙烯酸[2,5-双(对甲氧基苯甲酰氧基)苄酯]及聚甲基丙烯酸[2,5-双(对甲氧基苯甲酰氧基)苄酯]的合成, Synthesis of poly-[2,5-bis(4 '-methoxybenzoyloxy)benzyl acrylate] and poly-[2,5-bis(4 '-methoxybenzoyloxy)benzyl methacrylate]. 2000-01-01. |
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