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	相似分析-13 C核磁共振法鉴定(10,12,14)-十六碳共轭三烯-1-乙酸酯异构体的几何构型; Identification of Geometrical Isomers of Conjugated Hexadecatrienyl Acetates by Similarity Analysis-13 C-Nuclear Magnetic Resonance Spectra
	李西安 ; 袁谷
	2003
关键词	13 C核磁共振谱,相似分析法,(10,12,14)-十六碳共轭三烯-1-乙酸酯,几何构型 C-13-nuclear magnetic resonance spectroscopy similarity analysis (10,12,14)-hexadecatrienyl acetate geometrical configuration
英文摘要	报道了利用相似分析-13 C核磁共振法确定(10,12,14)-十六碳共轭三烯-1-乙酸酯异构体的几何构型.该方法将共轭三烯 6个烯碳的特征化学位移作为相似分析的基本参数, 计算样品与每一个几何异构体间的相似指数,根据最大相似指数确定样品最可能的构型.该方法简便,结果满意.; In this paper, a procedure is presented for identification of geometrical configuration of conjugated (10, 12, 14)-hexadecatrienyl acetates (sex pheromone and analogous) by similarity analysis-C-13-nuclear magnetic resonance spectra. In this method, the chemical shift of six olefinic carbons is defined as element parameters for similarity analysis, similarity index of any isomer is calculated in terms of each of the standard isomers, the configuration of isomer was assigned based on the maximum index. The method is easy and the result is satisfactory.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000182746400012&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 0; 4; 437-439; 31
语种	中文
出处	万方 ; SCI ; http://d.g.wanfangdata.com.cn/Periodical_fxhx200304013.aspx
出版者	分析化学
内容类型	其他
源URL	[http://hdl.handle.net/20.500.11897/46989]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	李西安,袁谷. 相似分析-13 C核磁共振法鉴定(10,12,14)-十六碳共轭三烯-1-乙酸酯异构体的几何构型, Identification of Geometrical Isomers of Conjugated Hexadecatrienyl Acetates by Similarity Analysis-13 C-Nuclear Magnetic Resonance Spectra. 2003-01-01.

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