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Multifunctional, Superelastic, and Lightweight MXene/Polyimide Aerogels
Liu, J; Zhang, HB; Xie, X2; Yang, R2; Liu, ZS; Liu, YF; Yu, ZZ
刊名SMALL
2018-11-08
卷号14期号:45页码:-
关键词electrical conductivity microwave absorption MXene aerogels superelasticity transition metal carbides and nitrides
ISSN号1613-6810
DOI10.1002/smll.201802479
英文摘要2D transition metal carbides and nitrides (MXenes) have gained extensive attention recently due to their versatile surface chemistry, layered structure, and intriguing properties. The assembly of MXene sheets into macroscopic architectures is an important approach to harness their extraordinary properties. However, it is difficult to construct a freestanding, mechanically flexible, and 3D framework of MXene sheets owing to their weak intersheet interactions. Herein, an interfacial enhancement strategy to construct multifunctional, superelastic, and lightweight 3D MXene architectures by bridging individual MXene sheets with polyimide macromolecules is developed. The resulting lightweight aerogel exhibits superelasticity with large reversible compressibility, excellent fatigue resistance (1000 cycles at 50% strain), 20% reversible stretchability, and high electrical conductivity of approximate to 4.0 S m(-1). The outstanding mechanical flexibility and electrical conductivity make the aerogel promising for damping, microwave absorption coating, and flexible strain sensor. More interestingly, an exceptional microwave absorption performance with a maximum reflection loss of -45.4 dB at 9.59 GHz and a wide effective absorption bandwidth of 5.1 GHz are achieved.
学科主题Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
语种英语
WOS记录号WOS:000449542800002
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/79828]  
专题金属研究所_中国科学院金属研究所
作者单位1.Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing Key Lab Adv Funct Polymer Composites, Beijing 100029, Peoples R China
2.Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Liu, J,Zhang, HB,Xie, X,et al. Multifunctional, Superelastic, and Lightweight MXene/Polyimide Aerogels[J]. SMALL,2018,14(45):-.
APA Liu, J.,Zhang, HB.,Xie, X.,Yang, R.,Liu, ZS.,...&Yu, ZZ.(2018).Multifunctional, Superelastic, and Lightweight MXene/Polyimide Aerogels.SMALL,14(45),-.
MLA Liu, J,et al."Multifunctional, Superelastic, and Lightweight MXene/Polyimide Aerogels".SMALL 14.45(2018):-.
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