The preferential retention of Zn-VI over Zn-IV on birnessite during dissolution/desorption | |
Qin, ZJ; Yin, H; Wang, XM![]() ![]() ![]() ![]() | |
刊名 | APPLIED CLAY SCIENCE
![]() |
2018 | |
卷号 | 161页码:169-175 |
关键词 | Zinc coordination Birnessite Dissolution Desorption Extended X-ray absorption fine structure spectroscopy |
ISSN号 | 0169-1317 |
DOI | 10.1016/j.clay.2018.04.017 |
文献子类 | Article |
英文摘要 | Zn is a common heavy metal in soils and sediments. In this study, the release behaviors of octahedral (Zn-IV) and tetrahedral (Zn-IV) Zn complexes on synthesized hexagonal birnessite were explored by solution chemistry method in combination with spectroscopic analysis. In acidic dissolution processes, the release of adsorbed Zn2+ from birnessite occurred into two stages: in the first stage, similar to 60% of Zn2+ was desorbed rapidly, with only 8% of Mn being released, and the ratio of Zn-VI/Zn-IV increased with time; in the second stage, the residual Zn2+ was mostly Zn-VI and released slowly at a nearly constant rate until complete dissolution of the matrix mineral was observed. During desorption of Zn2+ by Pb2+, the ratio of Zn-VI/Zn-IV on birnessite also increased, while the residual percentage of Zn-VI remained nearly constant. However, it is known that Zn-IV-triple corner-sharing (TCS) is more stable than Zn-VI-TCS, suggesting that part of the remaining Zn-IV-TCS on birnessite might transform to Zn-VI-TCS immediately when Zn-VI-TCS is replaced by H+ or Pb2+. Additionally, the possible distribution of Mn3+ and Zn-IV or the partial charge compensation by protons can lead to the preferential retention of Zn-IV on birnessite or the preferential re-adsorption of Zn-IV at the new edge sites. These results can provide new insights into the geochemical behavior of Zn2+ contaminant in soil and aquatic environments. |
电子版国际标准刊号 | 1872-9053 |
WOS关键词 | X-RAY-DIFFRACTION ; METAL SORBED BIRNESSITE ; NA-RICH BIRNESSITE ; BIOGENIC MN-OXIDES ; HEXAGONAL-BIRNESSITE ; MANGANESE OXIDE ; HEAVY-METALS ; PHYLLOMANGANATE NANOPARTICLES ; ABSORPTION SPECTROSCOPY ; FERROMANGANESE COATINGS |
WOS研究方向 | Chemistry ; Materials Science ; Mineralogy |
语种 | 英语 |
WOS记录号 | WOS:000436916600021 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/286084] ![]() |
专题 | 高能物理研究所_核技术应用研究中心 高能物理研究所_多学科研究中心 中国科学院高能物理研究所_中国散裂中子源 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Qin, ZJ,Yin, H,Wang, XM,et al. The preferential retention of Zn-VI over Zn-IV on birnessite during dissolution/desorption[J]. APPLIED CLAY SCIENCE,2018,161:169-175. |
APA | Qin, ZJ.,Yin, H.,Wang, XM.,Zhang, Q.,Lan, S.,...&郑黎荣.(2018).The preferential retention of Zn-VI over Zn-IV on birnessite during dissolution/desorption.APPLIED CLAY SCIENCE,161,169-175. |
MLA | Qin, ZJ,et al."The preferential retention of Zn-VI over Zn-IV on birnessite during dissolution/desorption".APPLIED CLAY SCIENCE 161(2018):169-175. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论