Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance | |
Li, BX; Liu PF(刘鹏飞); Zhu, QL; Wu, XT; Wu, LM; Liu, PF; Chen, H; Lin, H | |
刊名 | INORGANIC CHEMISTRY FRONTIERS |
2018 | |
卷号 | 5期号:6页码:1458-1462 |
ISSN号 | 2052-1553 |
DOI | 10.1039/c8qi00322j |
文献子类 | Article |
英文摘要 | The search for new non-centrosymmetric (NCS) crystals with wide energy-gaps (E-g) and strong second-harmonic generation (SHG) responses has become one of the greatest challenges in the mid- and far-infrared (MFIR) nonlinear optical (NLO) field. In this work, a novel quaternary NCS material Sr5ZnGa6S15 (SZGS), which contains a complex 3D anionic framework and possesses the optical properties required for the MFIR NLO applications, especially the good balance between wide E-g (3.15 eV) and large SHG response (d(ij) = 1.2 x AgGaS2), has been discovered for the first time. Moreover, the result of theoretical calculation further indicates that the 3D [ZnGa6S15](10-) framework makes definitive contributions to the NLO properties. All these studies demonstrate that SZGS is a promising NLO candidate in the MFIR region. |
WOS关键词 | 2ND-HARMONIC GENERATION RESPONSE ; LASER-DAMAGE THRESHOLDS ; METAL CHALCOGENIDES ; SE ; SULFIDES ; GE ; CRYSTAL ; GAP ; SN ; PREDICTION |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000435296200028 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/286073] |
专题 | 高能物理研究所_东莞分部 高能物理研究所_加速器中心 中国科学院高能物理研究所_中国散裂中子源 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Li, BX,Liu PF,Zhu, QL,et al. Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance[J]. INORGANIC CHEMISTRY FRONTIERS,2018,5(6):1458-1462. |
APA | Li, BX.,刘鹏飞.,Zhu, QL.,Wu, XT.,Wu, LM.,...&Lin, H.(2018).Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance.INORGANIC CHEMISTRY FRONTIERS,5(6),1458-1462. |
MLA | Li, BX,et al."Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance".INORGANIC CHEMISTRY FRONTIERS 5.6(2018):1458-1462. |
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