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One-step solid state synthesis of PtCo nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts
Tao JZ(陶举洲); Zhang SK(张晟恺); He CY(何春勇); Shen, PK; Zhang, SK; Tao, JZ; He, CY
刊名JOURNAL OF CATALYSIS
2018
卷号362页码:85-93
关键词PtCo nanocubes Graphene Core-shell structure Solid state synthesis Oxygen reduction reaction
ISSN号0021-9517
DOI10.1016/j.jcat.2018.03.025
文献子类Article
英文摘要Here, we report the synthesis of PtCo nanocubes with core-shell structure on graphene surface by a novel solid state method. Since no organic agent and surfactant was used during the synthesis process, the PtCo nanocubes surface is definite clean. The mean grain size of PtCo nanocubes is just about 5 nm, and PtCo nanocubes possess core-shell structure with PtCo core and a thin Pt-rich shell (about 3-5 atomic layers) on the surface. Compared with commercial Pt/C catalyst, the PtCo nanocubes exhibit an 8.4 times mass activity enhancement toward oxygen reduction reaction (ORR). Besides, the PtCo nanocubes show extreme high electrochemical durability. (C) 2018 Elsevier Inc. All rights reserved.
电子版国际标准刊号1090-2694
WOS关键词FUEL-CELL CATALYSTS ; CORE-SHELL NANOPARTICLES ; TRANSITION-METALS ; ALLOY CATALYSTS ; PLATINUM ; STABILITY ; CARBON ; TEMPERATURE ; MORPHOLOGY ; NANOWIRES
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000432770900011
内容类型期刊论文
源URL[http://ir.ihep.ac.cn/handle/311005/285937]  
专题高能物理研究所_东莞分部
高能物理研究所_实验物理中心
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Tao JZ,Zhang SK,He CY,et al. One-step solid state synthesis of PtCo nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts[J]. JOURNAL OF CATALYSIS,2018,362:85-93.
APA 陶举洲.,张晟恺.,何春勇.,Shen, PK.,Zhang, SK.,...&He, CY.(2018).One-step solid state synthesis of PtCo nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts.JOURNAL OF CATALYSIS,362,85-93.
MLA 陶举洲,et al."One-step solid state synthesis of PtCo nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts".JOURNAL OF CATALYSIS 362(2018):85-93.
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