Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates
Jie, JY; Liu, SY; Yu JP(于吉攀); Yu, JP; Yang, XB
刊名ADVANCED SYNTHESIS & CATALYSIS
2018
卷号360期号:2页码:267-271
关键词visible light induced radical migration trifluoromethylation enol triflate
ISSN号1615-4150
DOI10.1002/adsc.201701051
文献子类Article
英文摘要Herein, we reported a novel method to synthesize alpha-trifluoromethylated ketones from enol triflates. Involving a cascade sulfur dioxide extrusion and a CF3 (trifluoromethyl) radical addition process, this reaction proceeds at room temperature and is driven by visible light irradiation. This protocol bears good functional group compatibility, which can generate the desired products in good to excellent yields even in gram scale. It is hoped that this approach to generate CF3 radicals from enol triflates can be used in other radical-involved reactions.
电子版国际标准刊号1615-4169
WOS关键词RADICAL TRIFLUOROMETHYLATION ; ELECTROPHILIC TRIFLUOROMETHYLATION ; PHOTOREDOX CATALYSIS ; ROOM-TEMPERATURE ; OXIDATIVE TRIFLUOROMETHYLATION ; MEDIATED TRIFLUOROMETHYLATION ; CARBONYL-COMPOUNDS ; FUNCTIONAL-GROUPS ; HIGHLY EFFICIENT ; LANGLOIS REAGENT
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000422659800009
内容类型期刊论文
源URL[http://ir.ihep.ac.cn/handle/311005/285539]  
专题高能物理研究所_多学科研究中心
高能物理研究所_核技术应用研究中心
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Jie, JY,Liu, SY,Yu JP,et al. Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates[J]. ADVANCED SYNTHESIS & CATALYSIS,2018,360(2):267-271.
APA Jie, JY,Liu, SY,于吉攀,Yu, JP,&Yang, XB.(2018).Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates.ADVANCED SYNTHESIS & CATALYSIS,360(2),267-271.
MLA Jie, JY,et al."Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates".ADVANCED SYNTHESIS & CATALYSIS 360.2(2018):267-271.
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