Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates | |
Jie, JY; Liu, SY; Yu JP(于吉攀); Yu, JP; Yang, XB![]() | |
刊名 | ADVANCED SYNTHESIS & CATALYSIS
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2018 | |
卷号 | 360期号:2页码:267-271 |
关键词 | visible light induced radical migration trifluoromethylation enol triflate |
ISSN号 | 1615-4150 |
DOI | 10.1002/adsc.201701051 |
文献子类 | Article |
英文摘要 | Herein, we reported a novel method to synthesize alpha-trifluoromethylated ketones from enol triflates. Involving a cascade sulfur dioxide extrusion and a CF3 (trifluoromethyl) radical addition process, this reaction proceeds at room temperature and is driven by visible light irradiation. This protocol bears good functional group compatibility, which can generate the desired products in good to excellent yields even in gram scale. It is hoped that this approach to generate CF3 radicals from enol triflates can be used in other radical-involved reactions. |
电子版国际标准刊号 | 1615-4169 |
WOS关键词 | RADICAL TRIFLUOROMETHYLATION ; ELECTROPHILIC TRIFLUOROMETHYLATION ; PHOTOREDOX CATALYSIS ; ROOM-TEMPERATURE ; OXIDATIVE TRIFLUOROMETHYLATION ; MEDIATED TRIFLUOROMETHYLATION ; CARBONYL-COMPOUNDS ; FUNCTIONAL-GROUPS ; HIGHLY EFFICIENT ; LANGLOIS REAGENT |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000422659800009 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/285539] ![]() |
专题 | 高能物理研究所_多学科研究中心 高能物理研究所_核技术应用研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Jie, JY,Liu, SY,Yu JP,et al. Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates[J]. ADVANCED SYNTHESIS & CATALYSIS,2018,360(2):267-271. |
APA | Jie, JY,Liu, SY,于吉攀,Yu, JP,&Yang, XB.(2018).Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates.ADVANCED SYNTHESIS & CATALYSIS,360(2),267-271. |
MLA | Jie, JY,et al."Visible light induced Trifluoromethyl Migration: Easy Access to alpha-Trifluoromethylated Ketones from Enol Triflates".ADVANCED SYNTHESIS & CATALYSIS 360.2(2018):267-271. |
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