Ice as Solid Electrolyte to Conduct Various Kinds of Ions

doi:10.1002/anie.201907832

CORC > 化学研究所 > 中国科学院化学研究所

	Ice as Solid Electrolyte to Conduct Various Kinds of Ions
	Guo, Zeliang; Wang, Tianshuai; Wei, Hehe; Long, Yuanzheng; Yang, Cheng; Wang, Dong; Lang, Jialiang; Huang, Kai; Hussain, Naveed; Song, Chenxi
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2019-09-02
卷号	58 期号:36 页码:12569-12573
ISSN号	1433-7851
DOI	10.1002/anie.201907832
英文摘要	Water, considered as a universal solvent to dissolve salts, has been extensively studied as liquid electrolyte in electrochemical devices. The water/ice phase transition at around 0 degrees C presents a common phenomenon in nature, however, the chemical and electrochemical behaviors of ice have rarely been studied. Herein, we discovered that the ice phase provides efficient ionic transport channels and therefore can be applied as generalized solid-state ionic conductor. Solid state ionic conducting ices (ICIs) of Li+, Na+, Mg2+, Al3+, K+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, and Zn2+, frozen from corresponding sulphate solutions, exhibit ionic conductivities ranging from approximate to 10(-7) S cm(-1) (Zn2+) to approximate to 10(-3) S cm(-1) (Li+) at temperatures spanning from -20 degrees C to -5 degrees C. The discovery of ICIs opens new insight to design and fabrication of solid-state electrolytes that are simple, inexpensive, and versatile.
语种	英语
WOS记录号	WOS:000479872100001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/82687]
专题	中国科学院化学研究所
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Guo, Zeliang,Wang, Tianshuai,Wei, Hehe,et al. Ice as Solid Electrolyte to Conduct Various Kinds of Ions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(36):12569-12573.
APA	Guo, Zeliang.,Wang, Tianshuai.,Wei, Hehe.,Long, Yuanzheng.,Yang, Cheng.,...&Wu, Hui.(2019).Ice as Solid Electrolyte to Conduct Various Kinds of Ions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(36),12569-12573.
MLA	Guo, Zeliang,et al."Ice as Solid Electrolyte to Conduct Various Kinds of Ions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.36(2019):12569-12573.