Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine

doi:10.1021/acsami.9b09879

CORC > 化学研究所 > 中国科学院化学研究所

	Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine
	Shi, Jinbiao; Zhang, Jianling; Liang, Tongling; Tan, Dongxing; Tan, Xiuniang; Wan, Qiang; Cheng, Xiuyan; Zhang, Bingxing; Han, Buxing; Liu, Lifei
刊名	ACS APPLIED MATERIALS & INTERFACES
	2019-08-28
卷号	11 期号:34 页码:30953-30958
ISSN号	1944-8244
DOI	10.1021/acsami.9b09879
英文摘要	Metal-organic frameworks (MOFs) have attracted increased research attention in photocatalysis due to their great potential in light harvest and conversion. However, the organic transformations as photocatalyzed by MOFs under mild conditions yet remain a challenge. Herein, three bipyridylcontaining cadmium-organic frameworks Cd(dcbpy) (dcbpy = 2,2'-bipyridine-5,5'-dicarboxylate), Cd(bdc)(bpy) (bdc = 1,4-benzenedicarboxylate; bpy = 2,2'-bipyridyl), and Cd(bdc)(2Me-bpy) (2Me-bpy = 4,4'-dimethyl-2,2'-bipyridyl) were synthesized for the first time. The bpy-containing Cd-MOFs have strong light harvest abilities and suitable photocatalysis energy potentials, making them highly active and selective for the photo-oxidation of benzylamine to N-benzylbenzaldimine under mild conditions, i.e., using atmospheric air as oxidant, at room temperature, and in the absence of any photosensitizer or cocatalyst. It provides an efficient, economical, and green way for the direct oxidation of amines to produce imines.
语种	英语
WOS记录号	WOS:000484073400048
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/82627]
专题	中国科学院化学研究所
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Shi, Jinbiao,Zhang, Jianling,Liang, Tongling,et al. Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(34):30953-30958.
APA	Shi, Jinbiao.,Zhang, Jianling.,Liang, Tongling.,Tan, Dongxing.,Tan, Xiuniang.,...&Chen, Gang.(2019).Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine.ACS APPLIED MATERIALS & INTERFACES,11(34),30953-30958.
MLA	Shi, Jinbiao,et al."Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine".ACS APPLIED MATERIALS & INTERFACES 11.34(2019):30953-30958.