The high-efficiency and eco-friendly PEGylated ionic liquid systems for radioactive iodine capture through halogen bonding interaction
Xue, Zhimin1; Xue, Zhichao2,3
刊名JOURNAL OF MOLECULAR LIQUIDS
2017-07-01
卷号238页码:106-114
关键词PEGylated Iodine Halogen bonding Radioactive
ISSN号0167-7322
DOI10.1016/j.molliq.2017.04.126
通讯作者Xue, Zhimin(zmxue@bjfu.edu.cn)
英文摘要The kinetics of iodine uptake by eco-friendly PEGylated systems was investigated and the resutls showed that most of the systems could capture iodine from the solution of iodine in cyclohexane efficiently. For example, 86% of iodine could be captured in only 3 h by PEG200/NaI system. The efficiency of iodine uptake shows high correlation with the inorganic salts used which might be due to the halogen bonding (XB) interaction between the anion of salt with I-2. Besides that, the effect of organic solvents and ionic liquids on the iodine capture were also investigated. The results indicated that PEGylated systems are flexible and reobust for iodine capture, furthermore, they might be applied to other areas as solvents. (C) 2017 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[21503016]
WOS关键词METAL-ORGANIC FRAMEWORK ; WATER SORPTION ; VOLATILE IODINE ; DYNAMIC PROCESS ; REMOVAL ; CO2 ; THERMODYNAMICS ; ADSORPTION ; OXIDATION ; KINETICS
WOS研究方向Chemistry ; Physics
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000403854900015
资助机构National Natural Science Foundation of China
内容类型期刊论文
源URL[http://ir.igsnrr.ac.cn/handle/311030/63265]  
专题中国科学院地理科学与资源研究所
通讯作者Xue, Zhimin
作者单位1.Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Beijing 100101, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Xue, Zhimin,Xue, Zhichao. The high-efficiency and eco-friendly PEGylated ionic liquid systems for radioactive iodine capture through halogen bonding interaction[J]. JOURNAL OF MOLECULAR LIQUIDS,2017,238:106-114.
APA Xue, Zhimin,&Xue, Zhichao.(2017).The high-efficiency and eco-friendly PEGylated ionic liquid systems for radioactive iodine capture through halogen bonding interaction.JOURNAL OF MOLECULAR LIQUIDS,238,106-114.
MLA Xue, Zhimin,et al."The high-efficiency and eco-friendly PEGylated ionic liquid systems for radioactive iodine capture through halogen bonding interaction".JOURNAL OF MOLECULAR LIQUIDS 238(2017):106-114.
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