A mild and efficient cyanosilylation of ketones using in situ generated N-oxides-Ti(iPrO)(4) complexes as catalysts

	A mild and efficient cyanosilylation of ketones using in situ generated N-oxides-Ti(iPrO)(4) complexes as catalysts
	Shen, YC ; Feng, XM ; Li, Y ; Zhang, GL ; Jiang, YZ
刊名	SYNLETT
	2002
期号	5 页码:793_795
关键词	catalysis cyanosilylation ketones N-oxides complex
ISSN号	0936-5214
通讯作者	Feng, XM, Sichuan Univ, Fac Chem, Sichuan Key LGreen Chem & Technol, Chengdu 610064, Peoples R China.
产权排序	3
中文摘要	The addition of TMSCN to ketones catalyzed by complex of racemic N-(2'-pyridylmethyl)-2-diphenylhydroxymethylpyrrolidine N-oxide (rac-1) or N-benzyl-N,N-dihydroxyethylamine N-oxide and Ti(iPrO)(4) affords the racemic O-TMS cyanohydrins in good to excellent isolated yields (up to 97%) under mild reaction conditions.
学科主题	Chemistry, Organic
收录类别	SCI
语种	英语
WOS记录号	WOS:000175470400034
公开日期	2011-07-08
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/17269]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Shen, YC,Feng, XM,Li, Y,et al. A mild and efficient cyanosilylation of ketones using in situ generated N-oxides-Ti(iPrO)(4) complexes as catalysts[J]. SYNLETT,2002(5):793_795.
APA	Shen, YC,Feng, XM,Li, Y,Zhang, GL,&Jiang, YZ.(2002).A mild and efficient cyanosilylation of ketones using in situ generated N-oxides-Ti(iPrO)(4) complexes as catalysts.SYNLETT(5),793_795.
MLA	Shen, YC,et al."A mild and efficient cyanosilylation of ketones using in situ generated N-oxides-Ti(iPrO)(4) complexes as catalysts".SYNLETT .5(2002):793_795.