Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6–95 °C temperature range
Sa´ndor Kele;  Sebastian F.M. Breitenbach;  Enrico Capezzuoli;  A. Nele Meckler;  Martin Ziegler;  Isabel M. Millan;  Tobias Kluge;  Jo´zsef Dea´k;  Kurt Hanselmann;  Ce´dric M. John;  Hao Yan;  Zaihua Liu;  Stefano M. Berna
刊名Geochimica et Cosmochimica Acta
2015
卷号168页码:172-192
英文摘要

Conventional carbonate–water oxygen isotope thermometry and the more recently developed clumped isotope thermometer have been widely used for the reconstruction of paleotemperatures from a variety of carbonate materials. In spite of a large number of studies, however, there are still large uncertainties in both δ18O- and Δ47-based temperature calibrations. For this reason there is a need to better understand the controls on isotope fractionation especially on natural carbonates. In this study we analyzed oxygen, carbon and clumped isotopes of a unique set of modern calcitic and aragonitic travertines, tufa and cave deposits from natural springs and wells. Together these samples cover a temperature range from 6 to 95 °C. Travertine samples were collected close to the vents of the springs and from pools, and tufa samples were collected from karstic creeks and a cave. The majority of our vent and pool travertines and tufa samples show a carbonate–water oxygen isotope fractionation comparable to the one of Tremaine et al. (2011) with some samples showing higher fractionations. No significant difference between the calcite–water and aragonite–water oxygen isotope fractionation could be observed. The Δ47 data from the travertines show a strong relationship with temperature and define the regression Δ47 = (0.044 ± 0.005 × 106)/T2 + (0.205 ± 0.047). The pH of the parent solution, mineralogy and precipitation rate do not appear to significantly affect the Δ47-signature of carbonates, compared to the temperature effect and the analytical error. The tufa samples and three biogenic calcites show an excellent fit with the travertine calibration, indicating that this regression can be used for other carbonates as well. This work extends the calibration range of the clumped isotope thermometer to travertine and tufa deposits in the temperature range from 6 °C to 95 °C.

语种英语
内容类型期刊论文
源URL[http://ir.gyig.ac.cn/handle/42920512-1/9566]  
专题地球化学研究所_环境地球化学国家重点实验室
作者单位1.Gwis Ltd, Dunakeszi, Hungary
2.Geological Institute, ETH Zu¨rich, Switzerland
3.Institute for Geological and Geochemical Research, Research Centre for Astronomy and Earth Sciences, Hungarian Academy of Sciences, Budapest, Hungary
4.Dept. of Earth Sciences, Univ. of Cambridge, Downing Street, Cambridge CB2 3EQ, UK
5.Dept. of Physics and Geology, University of Perugia, Italy
6.Dept. of Earth Sci. and Eng., Qatar Carbonate and Carbon Storage Research Centre, Imperial College, London, London, Prince Consort Road, London SW7 2AZ, UK
7.Institute of Environmental Physics, Heidelberg University, Germany
8.State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
推荐引用方式
GB/T 7714
Sa´ndor Kele;Sebastian F.M. Breitenbach;Enrico Capezzuoli;A. Nele Meckler;Martin Ziegler;Isabel M. Millan;Tobias Kluge;Jo´zsef Dea´k;Kurt Hanselmann;Ce´dric M. John;Hao Yan;Zaihua Liu;Stefano M. Berna. Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6–95 °C temperature range[J]. Geochimica et Cosmochimica Acta,2015,168:172-192.
APA Sa´ndor Kele;Sebastian F.M. Breitenbach;Enrico Capezzuoli;A. Nele Meckler;Martin Ziegler;Isabel M. Millan;Tobias Kluge;Jo´zsef Dea´k;Kurt Hanselmann;Ce´dric M. John;Hao Yan;Zaihua Liu;Stefano M. Berna.(2015).Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6–95 °C temperature range.Geochimica et Cosmochimica Acta,168,172-192.
MLA Sa´ndor Kele;Sebastian F.M. Breitenbach;Enrico Capezzuoli;A. Nele Meckler;Martin Ziegler;Isabel M. Millan;Tobias Kluge;Jo´zsef Dea´k;Kurt Hanselmann;Ce´dric M. John;Hao Yan;Zaihua Liu;Stefano M. Berna."Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6–95 °C temperature range".Geochimica et Cosmochimica Acta 168(2015):172-192.
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