Synergistic use of NMR computation and quantitative interproton distance analysis in the structural determination of neokadcoccitane A, a rearranged triterpenoid featuring an aromatic ring D from Kadsura coccinea | |
Xu, Hou-Chao1,2,3; Hu, Kun1,2![]() ![]() ![]() | |
刊名 | ORGANIC CHEMISTRY FRONTIERS
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2019-05-21 | |
卷号 | 6期号:10页码:1619-1626 |
ISSN号 | 2052-4129 |
DOI | 10.1039/c9qo00281b |
通讯作者 | Puno, Pema-Tenzin(punopematenzin@mail.kib.ac.cn) |
英文摘要 | Neokadcoccitane A (1), an unprecedented 14(13. 12): 28(14. 8)-diabeo-3,4-secolanostane triterpenoid possessing an aromatic ring D and an unusual Me-21 orientation, along with two novel 14(13. 12)-abeo-3,4- seco-norlanostane triterpenoids featuring three-and one-carbon degradation, respectively (2 and 3), were isolated from the roots of Kadsura coccinea. The absolute configuration of 1 was determined by the synergistic use of NMR computation, quantitative interproton distance analysis, and TDDFT ECD calculation, while that of 2 was established using X-ray diffraction. 1 was found to exhibit moderate anti-platelet aggregation activity. |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000468001500011 |
内容类型 | 期刊论文 |
源URL | [http://ir.kib.ac.cn/handle/151853/67497] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
通讯作者 | Puno, Pema-Tenzin |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Yunnan Key Lab Nat Med Chem, Kunming 650201, Yunnan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Hou-Chao,Hu, Kun,Shi, Xiao-Huo,et al. Synergistic use of NMR computation and quantitative interproton distance analysis in the structural determination of neokadcoccitane A, a rearranged triterpenoid featuring an aromatic ring D from Kadsura coccinea[J]. ORGANIC CHEMISTRY FRONTIERS,2019,6(10):1619-1626. |
APA | Xu, Hou-Chao.,Hu, Kun.,Shi, Xiao-Huo.,Tang, Jian-Wei.,Li, Xiao-Nian.,...&Puno, Pema-Tenzin.(2019).Synergistic use of NMR computation and quantitative interproton distance analysis in the structural determination of neokadcoccitane A, a rearranged triterpenoid featuring an aromatic ring D from Kadsura coccinea.ORGANIC CHEMISTRY FRONTIERS,6(10),1619-1626. |
MLA | Xu, Hou-Chao,et al."Synergistic use of NMR computation and quantitative interproton distance analysis in the structural determination of neokadcoccitane A, a rearranged triterpenoid featuring an aromatic ring D from Kadsura coccinea".ORGANIC CHEMISTRY FRONTIERS 6.10(2019):1619-1626. |
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