Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells

doi:10.1016/j.materresbull.2004.07.004

CORC > 化学研究所 > 中国科学院化学研究所

	Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells
	Wang, GQ ; Zhou, XW ; Li, MY ; Zhang, JB ; Kang, JJ ; Lin, Y ; Fang, SB ; Xiao, XR
刊名	MATERIALS RESEARCH BULLETIN
	2004-11-02
卷号	39 期号:13 页码:2113-2118
关键词	Interface Polymers Impedance Spectroscopy Ionic Conductivity
ISSN号	0025-5408
DOI	10.1016/j.materresbull.2004.07.004
英文摘要	Gel polymer electrolytes were prepared by incorporating polyacrylonitrile (PAN) in a mixture of polysiloxane with quaternary ammonium side groups (PSQAS), ethylene carbonate (EC), propylene carbonate (PC) and iodine. The influence of PAN content on the ionic conductivity of gel polymer electrolytes and the charge-transfer kinetic performance in counterelectrode-electrolyte interface was investigated. The dye-sensitized solar cell with the gel polymer electrolyte containing 5 wt.% PAN showed the best photovoltaic performance; a maximum incident photon conversion efficiency of 63% at 520 nm was obtained, the short-circuit photocurrent density (J(sc)), the open- circuit voltage (V-oc) and the fill factor (FF) were 7 mA cm(-2), 0.565 V and 0.65, respectively. The corresponding overall conversion efficiency (eta) is 4.3%. (C) 2004 Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000224535000015
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/82367]
专题	中国科学院化学研究所
通讯作者	Lin, Y
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, GQ,Zhou, XW,Li, MY,et al. Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells[J]. MATERIALS RESEARCH BULLETIN,2004,39(13):2113-2118.
APA	Wang, GQ.,Zhou, XW.,Li, MY.,Zhang, JB.,Kang, JJ.,...&Xiao, XR.(2004).Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells.MATERIALS RESEARCH BULLETIN,39(13),2113-2118.
MLA	Wang, GQ,et al."Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells".MATERIALS RESEARCH BULLETIN 39.13(2004):2113-2118.