Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS](2)[CdI4] (DAMS=4-dimethylaminostyryl-1-methyl-pyridinium)

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	Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS](2)[CdI4] (DAMS=4-dimethylaminostyryl-1-methyl-pyridinium)
	Ren, P ; Qin, JG ; Chen, CT ; Zhang, DQ ; Hu, HM
刊名	JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
	2004-04-01
卷号	34 期号:4 页码:291-294
关键词	Solvothermal Synthesis Inorganic-organic Hybrid Crystal Structure
ISSN号	1074-1542
英文摘要	An inorganic-organic hybrid compound [DAMS](2)[CdI4] (DAMS=4-dimethyl-aminostyryl-1-methylpyridinium cation) was synthesized via the solvothermal reaction of equimolar CdI2 and DAMS.I- in a mixture of acetonitrile and H2O (2:1 in volume ratio) at 130degreesC. The product was characterized by X-ray single crystal structure analysis. The crystals of the title compound are triclinic, P-(1) over bar, with a=12.9849(19) Angstrom, b=13.1935(13) Angstrom, c=13.8792(10) Angstrom, alpha=106.798(6)degrees, beta=109.827(6)degrees, gamma=108.206(9)degrees, V=1906.0(4) Angstrom(3), Z=2. The cadmium atom was bonded to 4 iodine atoms to form a distorted tetrahedron, which was surrounded by DAMS cations. There exist pi-pi stacking interaction between the 2 adjacent antiparallelly arrayed DAMS cations.
语种	英语
出版者	KLUWER ACADEMIC/PLENUM PUBL
WOS记录号	WOS:000220601200012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/81833]
专题	中国科学院化学研究所
通讯作者	Qin, JG
作者单位	1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Beijing Ctr Crystal Res & Dev, Beijing, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Ren, P,Qin, JG,Chen, CT,et al. Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS](2)[CdI4] (DAMS=4-dimethylaminostyryl-1-methyl-pyridinium)[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,2004,34(4):291-294.
APA	Ren, P,Qin, JG,Chen, CT,Zhang, DQ,&Hu, HM.(2004).Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS](2)[CdI4] (DAMS=4-dimethylaminostyryl-1-methyl-pyridinium).JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,34(4),291-294.
MLA	Ren, P,et al."Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS](2)[CdI4] (DAMS=4-dimethylaminostyryl-1-methyl-pyridinium)".JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 34.4(2004):291-294.