Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene

doi:10.1002/pi.1236

CORC > 化学研究所 > 中国科学院化学研究所

	Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene
	Xue, H; Xu, YA; Ding, JY; Gao, LX; Ding, MX
刊名	POLYMER INTERNATIONAL
	2003-09-01
卷号	52 期号:9 页码:1423-1427
关键词	Atom Transfer Radical Polymerization Optically Active Polymer Specific Rotation 1 1 '-binaphthyl Moiety
ISSN号	0959-8103
DOI	10.1002/pi.1236
英文摘要	Atom transfer radical polymerization (ATPP) of (R)-2-methacryloyloxy-2'-methoxy-1,1'-binaphthalene ((R)-MAMBN) mediated by different amine ligands, copper(l) chloride and ethyl 2-bromopropionate in different solvents, and reverse ATRP of (R)-MAMBN were studied. It was shown that optically active polymers were obtained, with poor control of the molecular weights, and low polydispersities. Specific rotation of the polymers increased with increasing molecular weights. By comparison with (R)-MAMBN, poly((R)-MAMBN)s exhibits higher specific rotation and a positive Cotton effect. (C) 2003 Society of Chemical Industry.
语种	英语
出版者	JOHN WILEY & SONS LTD
WOS记录号	WOS:000185206400004
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/81113]
专题	中国科学院化学研究所
通讯作者	Ding, MX
作者单位	Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Xue, H,Xu, YA,Ding, JY,et al. Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene[J]. POLYMER INTERNATIONAL,2003,52(9):1423-1427.
APA	Xue, H,Xu, YA,Ding, JY,Gao, LX,&Ding, MX.(2003).Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene.POLYMER INTERNATIONAL,52(9),1423-1427.
MLA	Xue, H,et al."Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene".POLYMER INTERNATIONAL 52.9(2003):1423-1427.