Hydration of alkenes catalyzed by wool-palladium-iron complex

doi:10.1016/j.reactfunctpolym.2003.08.006

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	Hydration of alkenes catalyzed by wool-palladium-iron complex
	Jia, B; Yang, X; Huang, MY; Jiang, YY
刊名	REACTIVE & FUNCTIONAL POLYMERS
	2003
卷号	57 期号:2-3 页码:163-168
关键词	Biopolymer Wool-palladium-iron Complex Catalyst Hydration Alkenes Alcohols
ISSN号	1381-5148
DOI	10.1016/j.reactfunctpolym.2003.08.006
英文摘要	A new biopolymer-metal complex, wool-supported palladium-iron complex (wool-Pd-Fe), has been prepared and found to be a highly active catalyst for hydration of some alkenes to corresponding alcohols, such as allyl bromide to 1-bromo-2-propanol, allyl chloride to 1-chloro-2-propanol, allylamine to 1-amino-2-propanol, acrylonitrile to lactonitrile and cyclohexene to cyclohexanol in 95.0%, 87.5%, 90.6%, 75.3% and 98.2% yield, respectively, in the presence of water, butyl ether and phenol at 95 degreesC under 1 atm N-2. The yield was greatly affected by the Pd/Fe molar ratio in wool-Pd-Fe complex catalyst. And this catalyst was very stable and could be reused several times without remarkable change in the catalytic activity. (C) 2003 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000187666500010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/80975]
专题	中国科学院化学研究所
通讯作者	Jia, B
作者单位	Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Jia, B,Yang, X,Huang, MY,et al. Hydration of alkenes catalyzed by wool-palladium-iron complex[J]. REACTIVE & FUNCTIONAL POLYMERS,2003,57(2-3):163-168.
APA	Jia, B,Yang, X,Huang, MY,&Jiang, YY.(2003).Hydration of alkenes catalyzed by wool-palladium-iron complex.REACTIVE & FUNCTIONAL POLYMERS,57(2-3),163-168.
MLA	Jia, B,et al."Hydration of alkenes catalyzed by wool-palladium-iron complex".REACTIVE & FUNCTIONAL POLYMERS 57.2-3(2003):163-168.