Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods

doi:10.1002/pi.980

CORC > 化学研究所 > 中国科学院化学研究所

	Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods
	Xue, H; Xu, YA; Song, NH; Gao, LX; Ding, MX
刊名	POLYMER INTERNATIONAL
	2003-08-01
卷号	52 期号:8 页码:1321-1325
关键词	Anionic Polymerization Group Transfer Polymerization Free Radical Polymerization Optically Active Polymer
ISSN号	0959-8103
DOI	10.1002/pi.980
英文摘要	Optically active and racemic poly(meth)acrylates with pendant 1,1'-binaphthalene moiety of 2-methacryloyloxy- and 2-acryloyloxy-2'-methoxy-1,1'-binaphthalene (MAMBN and AMBN) were synthesized by anionic, group transfer and free radical polymerization methods. Their polymerizability and chiroptical properties are somewhat different, depending on the three types of polymerization methods used. The yields for poly(MAMBN)s are lower than for poly(AMBN)s. The optical rotation of the optically active polymers is identical to that of the corresponding monomers. The values of specific rotation of optically active poly(AMBN)s are much larger than those of optically active poly(MAMBN)s. (C) 2002 Society of Chemical Industry.
语种	英语
出版者	JOHN WILEY & SONS LTD
WOS记录号	WOS:000184478600013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/80909]
专题	中国科学院化学研究所
通讯作者	Ding, MX
作者单位	Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Xue, H,Xu, YA,Song, NH,et al. Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods[J]. POLYMER INTERNATIONAL,2003,52(8):1321-1325.
APA	Xue, H,Xu, YA,Song, NH,Gao, LX,&Ding, MX.(2003).Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods.POLYMER INTERNATIONAL,52(8),1321-1325.
MLA	Xue, H,et al."Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods".POLYMER INTERNATIONAL 52.8(2003):1321-1325.