Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex

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	Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex
	Miao, JH ; Yang, JH ; Chen, LY ; Huang, MY ; Jiang, YY
刊名	CHINESE CHEMICAL LETTERS
	2003-10-01
卷号	14 期号:10 页码:1008-1011
关键词	Wool-osmium Tetroxide Asymmetric Dihydroxylation Allylamine
ISSN号	1001-8417
英文摘要	A new chiral polymer-metal complex, wool-osmium tetroxide(wool-OsO4) complex was prepared by a very simple method. This complex was found to be able to catalyze the asymmetric dihydroxylation of allylamine to get (R)-(+)-3-amino-1, 2-propanediol. The experimental results showed that OsO4 content in the complex, reaction time, allylamine/OsO4 molar ratio all have great effects on the chemical and optical yields of product. Additionally, wool-OsO4 complex catalyst could be reused without remarkable change in optical catalytic activity.
语种	英语
出版者	CHINESE CHEMICAL SOCIETY
WOS记录号	WOS:000185983600007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/80703]
专题	中国科学院化学研究所
通讯作者	Miao, JH
作者单位	1.Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Miao, JH,Yang, JH,Chen, LY,et al. Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex[J]. CHINESE CHEMICAL LETTERS,2003,14(10):1008-1011.
APA	Miao, JH,Yang, JH,Chen, LY,Huang, MY,&Jiang, YY.(2003).Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex.CHINESE CHEMICAL LETTERS,14(10),1008-1011.
MLA	Miao, JH,et al."Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex".CHINESE CHEMICAL LETTERS 14.10(2003):1008-1011.