Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2) | |
Xu, W; Fang, Q; Xue, G; Yu, WT; Chen, HY; Liu, GQ; Xu, W; Xu, CY; Zhang, DQ; Zhu, DB | |
刊名 | CHINESE CHEMICAL LETTERS
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2003-10-01 | |
卷号 | 14期号:10页码:1089-1092 |
关键词 | Molecular Conductor Synthesis Electrical Conductivity Semiconductor Structure |
ISSN号 | 1001-8417 |
英文摘要 | A new molecular conductor (PyH)[Ni(dmit)(2)](2) (dmit = 4, 5-dimercapto-1, 3-dithiole-2-thione) has been prepared and its crystal structure has been determined. Crystallographic parameters for (PyH)[Ni(dmit)(2)](2): C17H6NNi2S20; triclinic system; P-I space group; a 5.9227 (4), b = 8.2279 (6), c = 16.7535 (9) Angstrom, alpha = 90.233 (5)degrees, beta = 92.107 (6)degrees, gamma = 104.654 (6)degrees; V = 789.25 (9) Angstrom(3); Z = 1; D-c = 2.068 g/cm(3);F(000) = 491. The conductivity atone direction on (001) plane at room temperature was measured to be 0.13 Omega(-1).cm(-1). The resistivity-temperature curve in the temperature range of 90similar to290 K shows that this compound behaves as a semiconductor. |
语种 | 英语 |
出版者 | CHINESE CHEMICAL SOCIETY |
WOS记录号 | WOS:000185983600030 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/80333] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Xu, W; Xu, W |
作者单位 | 1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, W,Fang, Q,Xue, G,et al. Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2)[J]. CHINESE CHEMICAL LETTERS,2003,14(10):1089-1092. |
APA | Xu, W.,Fang, Q.,Xue, G.,Yu, WT.,Chen, HY.,...&Zhu, DB.(2003).Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2).CHINESE CHEMICAL LETTERS,14(10),1089-1092. |
MLA | Xu, W,et al."Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2)".CHINESE CHEMICAL LETTERS 14.10(2003):1089-1092. |
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