Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study | |
Kong, DS; Wan, LJ; Han, MJ; Pan, GB; Lei, SB; Bai, CL; Chen, SH | |
刊名 | ELECTROCHIMICA ACTA
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2002-12-20 | |
卷号 | 48期号:4页码:303-309 |
关键词 | Adsorption Stm Au(111) Schiff Base Sam |
ISSN号 | 0013-4686 |
英文摘要 | The self-assembled monolayer (SAM) of Schiff base V-ape-V molecules on Au(I 11) in HClO4 solution has been investigated by electrochemical techniques and electrochemical scanning tunneling microscopy (ECSTM). The adsorption of V-ape-V on Au(I 11) retards the oxidization of Au and reduces the double-layer capacitance. Two-dimensional ordered molecular arrays with a (5 x 2root3) commensurate structure are observed. The V-ape-V molecules are adsorbed on Au(1 11) in a flat-lying orientation. A structural model is proposed to interpret the experimental results. (C) 2002 Elsevier Science Ltd. All rights reserved. |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000180408400002 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/79603] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wan, LJ |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China |
推荐引用方式 GB/T 7714 | Kong, DS,Wan, LJ,Han, MJ,et al. Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study[J]. ELECTROCHIMICA ACTA,2002,48(4):303-309. |
APA | Kong, DS.,Wan, LJ.,Han, MJ.,Pan, GB.,Lei, SB.,...&Chen, SH.(2002).Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study.ELECTROCHIMICA ACTA,48(4),303-309. |
MLA | Kong, DS,et al."Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study".ELECTROCHIMICA ACTA 48.4(2002):303-309. |
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