Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study

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	Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study
	Kong, DS ; Wan, LJ ; Han, MJ ; Pan, GB ; Lei, SB ; Bai, CL ; Chen, SH
刊名	ELECTROCHIMICA ACTA
	2002-12-20
卷号	48 期号:4 页码:303-309
关键词	Adsorption Stm Au(111) Schiff Base Sam
ISSN号	0013-4686
英文摘要	The self-assembled monolayer (SAM) of Schiff base V-ape-V molecules on Au(I 11) in HClO4 solution has been investigated by electrochemical techniques and electrochemical scanning tunneling microscopy (ECSTM). The adsorption of V-ape-V on Au(I 11) retards the oxidization of Au and reduces the double-layer capacitance. Two-dimensional ordered molecular arrays with a (5 x 2root3) commensurate structure are observed. The V-ape-V molecules are adsorbed on Au(1 11) in a flat-lying orientation. A structural model is proposed to interpret the experimental results. (C) 2002 Elsevier Science Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000180408400002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/79603]
专题	中国科学院化学研究所
通讯作者	Wan, LJ
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China
推荐引用方式 GB/T 7714	Kong, DS,Wan, LJ,Han, MJ,et al. Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study[J]. ELECTROCHIMICA ACTA,2002,48(4):303-309.
APA	Kong, DS.,Wan, LJ.,Han, MJ.,Pan, GB.,Lei, SB.,...&Chen, SH.(2002).Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study.ELECTROCHIMICA ACTA,48(4),303-309.
MLA	Kong, DS,et al."Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study".ELECTROCHIMICA ACTA 48.4(2002):303-309.