Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid

doi:10.1002/pat.175

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	Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid
	Liu, HW; Xin, F; Wu, LM; Huang, MY; Jiang, YY
刊名	POLYMERS FOR ADVANCED TECHNOLOGIES
	2002-03-01
卷号	13 期号:3-4 页码:210-215
关键词	Platinum Complex Catalysis Oxalic Acid Asymmetric Hydrogenation 2-butanone Itaconic Acid
ISSN号	1042-7147
DOI	10.1002/pat.175
英文摘要	A new silica-supported biopolymer-oxalic acid-Pt complex was prepared by a simple method. Methylcellulose (mc) reacted with oxalic acid in the presence of silica to give a complex SiO2-MC-(COOH)(2) on the surface of silica, then reacted with H2PtCl6.6H(2)O to form a Pt complex [SiO2-MC-(COOH)(2)-Pt]. This ocmplex was found to be able to catalyze the asymmetric hydrogenation of 2-butanone to (S)-(+)-2-butanol and itaconic acid to (S)-(-)-methylsuccinic, respectively, at room temperature and under 1 atm H-2. The experimental results showed that the product and optical yields were remarkable affected by the Pt content in the complex and the catalyst could be reused without any remarkable change in optical catalytic activity. Copyright (C) 2002 John Wiley Sons, Ltd.
语种	英语
出版者	JOHN WILEY & SONS LTD
WOS记录号	WOS:000174200300010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/78807]
专题	中国科学院化学研究所
通讯作者	Liu, HW
作者单位	Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Liu, HW,Xin, F,Wu, LM,et al. Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):210-215.
APA	Liu, HW,Xin, F,Wu, LM,Huang, MY,&Jiang, YY.(2002).Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),210-215.
MLA	Liu, HW,et al."Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):210-215.